(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2] 二甲基氨基二氯三(Μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(II)
CAS 204933-84-6 MFCD09753036
化学结构图
SMILES: [Cl-].Cl.CNC.C1CCCC2C(C3=C(C=CC4CCCCC=43)P(C3C=CC=CC=3)C3C=CC=CC=3)=C(C=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1.C1CCCC2C(C3=C(C=CC4CCCCC=43)P(C3C=CC=CC=3)C3C=CC=CC=3)=C(C=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2
化学属性
| Mol. Formula | (CH3)2NH2+[C88H80Cl5P4Ru2]- |
|---|---|
| Mol. Weight | 1686.97 |
| Appearance | red-brown pwdr. |
| Stability | air sensitive |
| Melting Point | >100°C dec. |
别名和识别编码
| Chemical Name | (R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2] |
|---|---|
| Synonym | (S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2] 二甲铵二氯三(μ-氯)二[(R)-(+)-2,2′-二(二苯基膦基)-5,5′,6,6′,7,7′,8,8′-八氢-1,1′-联萘基]二钌酸盐(II) |
| CAS Number | 944451-12-1 |
| MDL Number | MFCD09753036 |
| PubChem Substance ID | 329761473 |
| Chemical Name Translation | 二甲基氨基二氯三(Μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(II) |
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分类
- {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
