Dimethylammonium Dichlorotri(μ-Chloro)Bis[(S)-(-)-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl]Diruthenate(II) 二甲基铵二氯三(μ-氯)双[(S)-(-)-2,2-双(二苯基膦基)-1,1-联萘基]二钌(II)
CAS 199541-17-8 MFCD09753033
化学结构图
SMILES: [Cl-].Cl.CNC.C1=CC(=C(C2=C(C=CC3C=CC=CC=32)P(C2C=CC=CC=2)C2C=CC=CC=2)C2C=CC=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC(=C(C2=C(C=CC3C=CC=CC=32)P(C2C=CC=CC=2)C2C=CC=CC=2)C2C=CC=CC=21)P(C1C=CC=CC=1)C1C=CC=CC=1.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2
化学属性
| Mol. Formula | (CH3)2NH2+[C88H64Cl5P4Ru2]- |
|---|---|
| Mol. Weight | 1670.84 |
| Appearance | orange pwdr. |
| Stability | air sensitive |
| Melting Point | >100°C dec. |
别名和识别编码
| Chemical Name | Dimethylammonium Dichlorotri(μ-Chloro)Bis[(S)-(-)-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl]Diruthenate(II) |
|---|---|
| Synonym | 二甲铵二氯三(μ-氯)二[(R)-(+)-2,2′-二(二苯基膦基)-1,1′-联萘基]二钌酸盐(II) (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2] 二甲基铵二氯三(μ-氯)二[(S)-(-)-2,2′-二(二苯基膦基)-1,1′-联萘基]二钌酸盐(II) |
| CAS Number | 199541-17-8 |
| MDL Number | MFCD09753033 |
| Chemical Name Translation | 二甲基铵二氯三(μ-氯)双[(S)-(-)-2,2-双(二苯基膦基)-1,1-联萘基]二钌(II) |
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分类
- {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
相关文献及参考
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- H228 Flammable solid 易燃固体
- R11 Highly flammable 非常易燃
