Diacetato[(R)-(+)-2,2’-Bis(Di-P-Tolylphosphino)-1,1’-Binaphthyl]Ruthenium(II) [(R)-(+)-2,2’-双(二对甲苯基膦)-1,1’-联萘]钌二乙酸盐

CAS 116128-29-1 MFCD09753021

化学结构图

116128-29-1
SMILES:

化学属性

Mol. FormulaC52H46O4P2Ru
Mol. Weight897.94
Appearance brown pwdr.
Stabilityair sensitive
Melting Point>100°C dec.

别名和识别编码

Chemical NameDiacetato[(R)-(+)-2,2’-Bis(Di-P-Tolylphosphino)-1,1’-Binaphthyl]Ruthenium(II)
Synonym 二乙酸[(R)-2,2′-二(二对甲苯膦酰)-1,1′-联萘]钌(II) 二乙酸根[(S)-(-)-2,2′-双(二-对甲苯膦酰)-1,1′-联萘]钌(II)
MDL NumberMFCD09753021
CAS Number106681-15-6
Chemical Name Translation[(R)-(+)-2,2’-双(二对甲苯基膦)-1,1’-联萘]钌二乙酸盐
PubChem Substance ID354334079
Reaxys-RN14403406
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性

系列性分类


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