(S)-DTBM-SEGPHOS (S)-5,5'-二[二(3,5-二叔丁基-4-甲氧基苯基)膦基]-4,4'-联苯并二恶茂
CAS 210169-40-7 MFCD09753003
化学结构图
SMILES: COc1c(C(C)(C)C)cc(P(c2cc(C(C)(C)C)c(OC)c(C(C)(C)C)c2)c2ccc3c(c2-c2c(P(c4cc(C(C)(C)C)c(OC)c(C(C)(C)C)c4)c4cc(C(C)(C)C)c(OC)c(C(C)(C)C)c4)ccc4c2OCO4)OCO3)cc1C(C)(C)C
化学属性
| Mol. Formula | C74H100O8P2 |
|---|---|
| Mol. Weight | 1179.53 |
| Appearance | off-white pwdr. |
| Melting Point | 126-128°C |
别名和识别编码
| Chemical Name | (S)-DTBM-SEGPHOS |
|---|---|
| Synonym | (R)-(-)-5,5′-双[二(3,5-二叔丁基-4-甲氧基苯基)膦]-4,4′-二-1,3-苯并二噁茂 [(4R)-(4,4′-二-1,3-苯并二噁茂)-5,5′-二基]二[双(3,5--二叔丁基-4-甲氧基苯基)膦] (R)-DTBM-SEGPHOS® (S)-(+)-5,5′-双[二(3,5-二叔丁基-4-甲氧基苯基)膦]-4,4′-二-1,3-苯并二噁茂 |
| MDL Number | MFCD09753003 |
| CAS Number | 210169-40-7 |
| Chemical Name Translation | (S)-5,5'-二[二(3,5-二叔丁基-4-甲氧基苯基)膦基]-4,4'-联苯并二恶茂 |
| Reaxys-RN | 22806358 |
| PubChem Substance ID | 329761548 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
相关文献及参考
- Duan, Z.-C.; et al., Cu-catalyzed asymmetric conjugate reduction of β-substituted α,β-unsaturated phosphonates: an efficient synthesis of optically active β-stereogenic Tetrahedron Lett. 50 , 6720-6722, (2009)
- Moser, R.; et al., CuH-Catalyzed Enantioselective 1,2-Reductions of a,ß-Unsaturated Ketones J. Am. Chem. Soc. 132 , 7852-7853, (2010)
- Nishida, G.; et al., Enantioselective synthesis of P-stereogenic alkynylphosphine oxides by Rh-catalyzed [2+2+2] cycloaddition Angew. Chem. Int. Ed. Engl. 47 , 3410-3413, (2008)
- Seiser, T.; Cramer, N., Enantioselective C-C bond activation of allenyl cyclobutanes: access to cyclohexenones with quaternary stereogenic centers Angew. Chem. Int. Ed. Engl. 47 , 9294-9297, (2008)
- Seiser, T.; Cramer, N., Rhodium(I)-Catalyzed Enantioselective Activation of Cyclobutanols: Formation of Cyclohexane Derivatives with Quaternary Stereogenic Centers Chem. Eur. J. 16 , 3383-3391, (2010)
