(R)-2-(Diphenyl((trimethylsilyl)oxy)methyl)pyrrolidine (R)-2-(二苯基((三甲基硅烷基)-氧基)甲基)吡咯烷
CAS 943757-71-9 MFCD09265100
化学结构图
SMILES: C[Si](C)(C)OC(c1ccccc1)(c1ccccc1)C1CCCN1
化学属性
| Mol. Formula | C20H27NOSi |
|---|---|
| Mol. Weight | 325.53 |
| Density | 1.0459 g/mL at 25 °C |
| Refractive index | 1.5480 to 1.5520 |
| Appearance | white to light brown viscous liq. |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | (R)-2-(Diphenyl((trimethylsilyl)oxy)methyl)pyrrolidine |
|---|---|
| Synonym | (R)-α,α-二苯基脯氨醇三甲基硅基醚 溶液 (R)-α,α-二苯基脯氨醇三甲基硅基醚 (R)-(+)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚 (2R)-2-[二苯基[(三甲基硅基)氧基]甲基]吡咯烷 (R)-(+)-α,α-二苯基-2-吡咯烷甲醇三甲基硅基醚 溶液 (2R)-2-[二苯基[(三甲基硅基)氧基]甲基]吡咯烷 (R)-α,α-二苯基脯氨醇三甲基硅基醚 (R)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine (R)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine (R)-2-[二苯基(三甲基硅烷氧基)甲基]吡咯烷 溶液 |
| MDL Number | MFCD09265100 |
| PubChem Substance ID | 354334881 |
| Chemical Name Translation | (R)-2-(二苯基((三甲基硅烷基)-氧基)甲基)吡咯烷 |
| CAS Number | 943757-71-9 |
| Reaxys-RN | 15634082 |
| InChI | InChI=1S/C20H27NOSi/c1-23(2,3)22-20(19-15-10-16-21-19,17-11-6-4-7-12-17)18-13-8-5-9-14-18/h4-9,11-14,19,21H,10,15-16H2,1-3H3/t19-/m1/s1 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Proline-Based Organocatalysts
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
