(S)-(+)-2,2’-Bis[di(3,5-Di-T-Butyl-4-Methoxyphenyl)Phosphino]-6,6’-Dimethoxy-1,1’-Biphenyl (S)-(6,6’-二甲氧基联苯-2,2’-二基)二[双(3,5-二-叔丁基-4-甲氧苯基)膦]
CAS 910134-30-4 MFCD09265029
化学结构图
SMILES:
化学属性
| Mol. Formula | C74H104O6P2 |
|---|---|
| Mol. Weight | 1151.56 |
| Appearance | white xtl. |
别名和识别编码
| Chemical Name | (S)-(+)-2,2’-Bis[di(3,5-Di-T-Butyl-4-Methoxyphenyl)Phosphino]-6,6’-Dimethoxy-1,1’-Biphenyl |
|---|---|
| Synonym | (S)-3,5-t-Bu-4-MeO-MeOBIPHEP (R)-(6,6′-二甲氧基联苯-2,2′-二基)二[双(3,5-二-叔丁基-4-甲氧苯基)膦] (S)-(6,6′-二甲氧基联苯-2,2′-二基)二[双(3,5-二-叔丁基-4-甲氧苯基)膦] SL-A109-2 (R)-3,5-t-Bu-4-MeO-MeOBIPHEP (R)-[6,6′-二甲氧基(1,1′-联苯基)-2,2′-二基]二{双[3,5-二(1,1-二甲基乙基)-4-甲氧苯基]膦} SL-A109-1 (S)-[6,6′-二甲氧基(1,1′-联苯基)-2,2′-二基]二{双[3,5-二(1,1-二甲基乙基)-4-甲氧苯基]膦} (S)-[6,6′-二甲氧基(1,1′-联苯基)-2,2′-二基]二{双[3,5-二(1,1-二甲基乙基)-4-甲氧苯基]膦} (S)-3,5-t-Bu-4-MeO-MeOBIPHEP SL-A109-2 |
| MDL Number | MFCD09265029 |
| CAS Number | 910134-30-4 |
| Chemical Name Translation | (S)-(6,6’-二甲氧基联苯-2,2’-二基)二[双(3,5-二-叔丁基-4-甲氧苯基)膦] |
| PubChem Substance ID | 329753360 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, MeOBIPHEP Ligands, Privileged Ligands and Complexes, Solvias Ligands and Complexes
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, MeOBIPHEP Ligands, Privileged Ligands and Complexes, Solvias Ligands and Complexes
相关文献及参考
- 1. Le Boucher d'Herouville, F.; et al., Room-temperature Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to maleimides and enones in the presence of CF3-substituted MeOBIPHEP analogues J. Org. Chem. 76 , 6925-6930, (2011) 摘要
- 2. Shen, Z.; et al., Mechanistic insights into the rhodium-catalyzed intramolecular ketone hydroacylation J. Am. Chem. Soc. 131 , 1077-1091, (2009) 摘要
- 3. Seiser, T.; Cramer, N., Enantioselective C-C bond activation of allenyl cyclobutanes: access to cyclohexenones with quaternary stereogenic centers Angew. Chem. Int. Ed. Engl. 47 , 9294-9297, (2008)
- 4. Zhou, J.; Hartwig, J. F., Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity J. Am. Chem. Soc. 130 , 12220-12221, (2008) 摘要
- 5. Navarre, L.; et al., Access to enantioenriched a-amino esters via rhodium-catalyzed 1,4-addition/enantioselective protonation J. Am. Chem. Soc. 130 , 6159, (2008)
