(-)-2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-(3,5-dimethylphenyl)maleimide(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS N/A MFCD07782014
化学结构图
SMILES: [Rh+].CC1=CC(=CC(C)=C1)N1C(=O)C(=C(C1=O)P1[C@H](C)CC[C@H]1C)P1[C@H](C)CC[C@H]1C.F[B-](F)(F)F.C1CC=CCCC=C1
化学属性
| Mol. Formula | C32H45BF4NO2P2Rh |
|---|---|
| Mol. Weight | 727.36 |
别名和识别编码
| Chemical Name | (-)-2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-(3,5-dimethylphenyl)maleimide(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate |
|---|---|
| Synonym | 3,4-双[(2R,5R)-2,5-二甲基磷烷基]-1-(3,5-二甲苯基]-1H-吡咯-2,5-二酮(1,5-环辛二烯)四氟硼酸铑(I) catASium® MNXyl(R)Rh (-)-2,3-双[(2R,5R)-2,5-二甲基磷]-N-(3,5-二甲苯基)马来酰亚胺(1,5-环辛二烯)四氟硼酸铑(I) |
| MDL Number | MFCD07782014 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, catASium
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, catASium
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
