1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5-dihydro-4-oxazolyl)methyl]diphenylphosphinite κN:κP}iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate ((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I)
CAS 405235-55-4 MFCD06658140
化学结构图
SMILES: [Ir+].C[C@@H]1OC(=N[C@@H]1C(CC1=CC=CC=C1)(CC1=CC=CC=C1)OP(C1=CC=CC=C1)C1=CC=CC=C1)C1=CC=CC=C1.FC(F)(F)C1=CC(=CC(=C1)[B-](C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)(C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C1=CC(=CC(=C1)C(F)(F)F)C(F)(F)F)C(F)(F)F.C1C[CH][CH]CC[CH][CH]1 |^1:101,102,105,106|
化学属性
| Mol. Formula | C77H58BF24IrNO2P |
|---|---|
| Mol. Weight | 1719.25 |
| Appearance | orange pwdr. |
| Stability | air sensitive, store cold |
| Melting Point | 112-113°C |
别名和识别编码
| Chemical Name | tetrakis(3,5-bis(trifluoromethyl)phenylborate, min. 97% (S,S)-[COD]Ir[Ph2PThrePHOX] |
|---|---|
| Synonym | ThrePHOX ThrePHOX Ubaphox [((4S,5S)-Ph2-Ubaphox)Ir(COD)]BARF Ubaphox [((4S,5S)-Ph2-Ubaphox)Ir(COD)]BARF |
| MDL Number | MFCD06658140 |
| PubChem Substance ID | 329761386 |
| CAS Number | 405235-55-4 |
| Chemical Name Translation | ((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-diphenylphosphinite)(1,5-COD)iridium(I) |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, PHOX, Privileged Ligands and Complexes, Solvias Ligands and Complexes, Ubaphox
