R-(-)-1 13-Bis(Diphenylphosphino)-7 8-Dihydro-6H-Dibenzo[F H][1 5]Dioxonin (R)-C3-Tunephos (R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷
CAS 301847-89-2 MFCD06658115
化学结构图
SMILES: C1CCOC2C=CC=C(C=2C2C(=CC=CC=2O1)P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C39H32O2P2 |
|---|---|
| Mol. Weight | 594.62 |
| Melting Point | 153-161 °C(lit.) |
| Appearance | white pwdr. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | R-(-)-1 13-Bis(Diphenylphosphino)-7 8-Dihydro-6H-Dibenzo[F H][1 5]Dioxonin (R)-C3-Tunephos |
|---|---|
| Synonym | (R)-(-)-1,13-二(二苯基膦)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬四烯 (R)-C3-TunePhos |
| MDL Number | MFCD06658115 |
| PubChem Substance ID | 24883784 |
| CAS Number | 301847-89-2 |
| Chemical Name Translation | (R)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Chiral Quest Ligands and Complexes, Privileged Ligands and Complexes
相关文献及参考
- 1. Li, W.; et al., Highly Efficient and Highly Enantioselective Asymmetric Hydrogenation of Ketones with TunePhos/1,2-Diamine-Ruthenium(II) Complexes J. Org. Chem. 74 , 1397-1399, (2009)
- 2. Wu, S.; et al., Highly Enantioselective Hydrogenation of Enol Acetates Catalyzed by Ru-TunaPhos Complexes Org. Lett. 4 , 4495-4497, (2002)
- 3. Kim, I. S.; et al., Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition J. Am. Chem. Soc. 130 , 14891-14899, (2008)
- 4. Wang, C.-J.; et al., Highly enantioselective hydrogenation of a-keto esters catalyzed by Ru-tunephos complexes Synlett , 1169-1172, (2006)
- 5. Zhang, Z. et al. J. Org. Chem. 65 , 6223, (2000) 摘要
- 6. Tang, W. et al. J. Am. Chem. Soc. 125 , 9570, (2003) 摘要
- 7. Lei, A. et al. J. Am. Chem. Soc. 126 , 1626, (2004) 摘要
