(3S,CIS)-(+)-2,3-DIHYDRO-3-ISOPROPYL-7A-METHYLPYRROLO[2,1-B] OXAZOL-5(7AH)-ONE (3S-顺式)-(+)-2,3-二氢-3-异丙基-7a-甲基吡咯并[2,1-b]氧氮杂茂-5(7aH)-酮
CAS 116910-11-3 MFCD06496252
化学结构图
SMILES: CC(C)[C@H]1CO[C@]2(C)C=CC(=O)N21
化学属性
| Mol. Formula | C10H15NO2 |
|---|---|
| Mol. Weight | 181.23 |
| Melting Point | 46-49 °C(lit.) |
别名和识别编码
| Chemical Name | (3S-cis)-(+)-2,3-Dihydro-3-isopropyl-7a-methylpyrrolo[2,1-b]oxazol-5(7aH)-one |
|---|---|
| MDL Number | MFCD06496252 |
| PubChem Substance ID | 24869479 |
| CAS Number | 116910-11-3 |
| Chemical Name Translation | (3S-顺式)-(+)-2,3-二氢-3-异丙基-7a-甲基吡咯并[2,1-b]氧氮杂茂-5(7aH)-酮 |
| Synonym | (3S-顺式)-(+)-2,3-二氢-3-异丙基-7a-甲基吡咯并[2,1-b]氧氮杂茂-5(7aH)-酮 |
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资金保障
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Others
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Others
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Other Heterocyclic Building Blocks
相关文献及参考
- 1. Romo, D. Meyers, A.I. Tetrahedron 47 , 9503, (1991)
- 2. Fray, A.H. Meyers, A.I. J. Org. Chem. 61 , 3362, (1996)
- 3. Meyers, A.I. et al. J. Org. Chem. 60 , 4359, (1995)
- 4. Munchhoff, M.J. Meyers, A.I. J. Org. Chem. 60 , 7084, (1995)
- 5. Munchhoff, M.J. Meters, A.I. J. Org. Chem. 60 , 7086, (1995)
- 6. Sandham, D.A. Meyers, A.I. J. Chem. Soc., Chem. Commun. , 2511, (1995)
- 7. Andres, C.S. Meyers, A.I. Tetrahedron Lett. 36 , 3491, (1995)
- 8. Andres, C.J. et al. Tetrahedron Lett. 60 , 3189, (1995)
- 9. Brengel, G.P. Meyers, A.I. J. Org. Chem. 61 , 3230, (1996)
- 10. Meyers, A.I. et al. J. Org. Chem. 61 , 2586, (1996) 摘要
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
