1,2-Bis((R)-(2-Methoxyphenyl)(Phenyl)Phosphino)Ethane (1R,2R)-双[(2-甲氧基苯基)苯基磷]乙烷

CAS 55739-58-7 MFCD05863546

化学结构图

55739-58-7
SMILES: COC1=CC=CC=C1[P@](CC[P@@](C1=CC=CC=C1OC)C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC28H28O2P2
Mol. Weight458.48
Melting Point102.0 to 106.0 deg-C
TSCANo
Density1.422
Appearance white xtl.

别名和识别编码

Chemical Name1,2-Bis((R)-(2-Methoxyphenyl)(Phenyl)Phosphino)Ethane
Synonym (R,R)-1,2-双[(2-甲氧基苯基)(苯基膦基)]乙烷 (R,R)-DIPAMP (R,R)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦] (R,R)-DIPAMP,(R,R)-乙烯二[(2-甲氧基苯基)苯基膦] (R,R)?-?1,2-?乙烷二基双[(2-?甲氧基苯基)?苯基膦] (R,R)?-?1,2-?双[(2-?甲氧基苯基)?(苯基膦基)?]?乙烷 [(1R,2R)?-?(-?)?-?双[(2-?甲氧基苯基)?苯基膦]?乙烷] (R,R)-乙烯二[(2-甲氧基苯基)苯基膦] (R,R)-1,2-乙烷二基双[(2-甲氧基苯基)苯基膦] (R,R)-1,2-双[(2-甲氧基苯基)(苯基膦基)]乙烷 [(1R,2R)-(-)-双[(2-甲氧基苯基)苯基膦]乙烷] (R,R)-乙烯二[(2-甲氧基苯基)苯基膦] (1R,2R)-(-)-Bis[(2-methoxyphenyl)phenylphosphino]ethane [(1R,2R)-(-)-双[(2-甲氧基苯基)苯基膦]乙烷]
MDL NumberMFCD05863546
PubChem Substance ID87559703
CAS Number55739-58-7
Reaxys-RN2919293
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation(1R,2R)-双[(2-甲氧基苯基)苯基磷]乙烷
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DIPAMP, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DIPAMP, Privileged Ligands and Complexes

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DIPAMP - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DIPAMP - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. DIOP
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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