2-Dicyclohexylphosphino-2,6-Dimethoxy-1,1-Biphenyl 2-双环己基膦-2′,6′-二甲氧基联苯

CAS 657408-07-6 MFCD05861611

化学结构图

657408-07-6
SMILES: COc1cccc(OC)c1-c1ccccc1P(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC26H35O2P
Mol. Weight410.54
Melting Point163.0 to 167.0 deg-C
TSCANo
Density1.93
Appearance white xtl.
RedoxReduction
Danger-Level-
pH-:-

别名和识别编码

Chemical Name2-Dicyclohexylphosphino-2,6-Dimethoxy-1,1-Biphenyl
CAS Number657408-07-6
Alfabeta NameDICYCLOHEXYLDIMETHOXYBIPHENYLYLPHOSPHINE 26112[]()-----,,'''
MDL NumberMFCD05861611
Synonym S-PHOS SPhos 2-二环己基膦-2′,6′-二甲氧基联苯浸渍片 S-Phos 浸渍片 2-双环己基膦-2′,6′-二甲氧基联苯 2-双环己基膦-2' 2-双环己基膦-2',6'-二甲氧基联苯 2-二环己基膦-2′,6′-二甲氧基联苯浸渍片 S-Phos 浸渍片 ChemDose™，S-Phos 片 S-Phos，ChemDose™ 片 6'-二甲氧基联苯 ChemDose™，S-Phos 片
PubChem Substance ID11269872
Chemical Name Translation2-双环己基膦-2′,6′-二甲氧基联苯
LabNetwork Molecule IDLN00155052
Reaxys-RN10118080
InChIInChI=1S/C26H35O2P/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21/h9-11,16-21H,3-8,12-15H2,1-2H3
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分类

  • {SNA} Buchwald Ligands, Catalysis, Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosp
  • {SNA} Buchwald Ligands, Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Phosphine Compounds
  • {SNA} Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, ChemDose, Chemical Synthesis, Cross-Coupling, Specialty Synthesi

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P333+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Signal word Warning
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Hazard Codes Xn
Risk Statements
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive
Restrict -

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. ChemDose™ - Specialty Synthesis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Buchwald Ligands Buchwald 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Functional Group 官能团索引
  2. phosphine
  1. Buchwald Precatalysts & Ligands
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Buchwald Precatalysts & Ligands
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Phosphine
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Buchwald Precatalysts & Ligands
  2. 96-5485 Buchwald Biaryl Phosphine Ligand Mini Kit 1 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. 96-5485 Buchwald Biaryl Phosphine Ligand Mini Kit 1 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Phosphine
  2. 96-5485 Buchwald Biaryl Phosphine Ligand Mini Kit 1 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. Phosphorus
  3. Buckwad Ligands/偶联C-N键生成

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