2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine 2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-D]恶唑啉-2-基]吡啶

CAS 185346-09-2 MFCD05861599

化学结构图

185346-09-2
SMILES: C1[C@H]2OC(=N[C@H]2C2C=CC=CC=21)C1C=CC=C(N=1)C1=N[C@@H]2[C@@H](CC3C=CC=CC=32)O1

化学属性

Mol. FormulaC25H19N3O2
Mol. Weight393.44
Melting Point276-281
Appearance white-light yellow pwdr. white to off-white pwdr.
Stabilitystore cold

别名和识别编码

Chemical Name2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
Synonym (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aS,8aR)-in-pybox Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(ΙΙ) (3aS,3′aS,8aR,8′aR)-2,2′-(2,6-吡啶二基)双[3a,8a-二氢-8H-茚并[1,2-d]噁唑 (3aS,8aR)-in-pybox Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(dip-tolylphosphino)1,1'-binaphthyl]diruthenate(ΙΙ) (3aS,8aR)-in-pybox (3aS,8aR)-in-pybox Dimethlyammonium dichlorotri(μ-chloro)bis[(S)-(−)-2,2′-bis(dip-tolylphosphino)1,1′-binaphthyl]diruthenate(ΙΙ) 2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-d]噁唑啉-2-基]吡啶
MDL NumberMFCD05861599
CAS Number185346-09-2
Chemical Name Translation2,6-双[(3aS,8aR)-3a,8a-二氢-8H-茚并[1,2-D]恶唑啉-2-基]吡啶
PubChem Substance ID329760573
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX

相关文献及参考

  • 1. E. Milczek, et al., , Enantioselective C-H amination using cationic ruthenium(II)-pybox catalysts Angew. Chem. Int. Ed. Engl. 47 , 6825-6828, (2008)
  • 2. D. A. Evans and K. R. Fandrick, , Catalytic Enantioselective Pyrrole Alkylations of a,ß-Unsaturated 2-Acyl Imidazoles Org. Lett. 8 , 2249-2252, (2006)
  • 3. M. K. Tse, et al., , Ruthenium-catalyzed asymmetric epoxidation of olefins using H2O2, part I: synthesis of new chiral N,N,N-tridentate pybox and pyboxazine ligands and their ruthenium complexes Chem. Eur. J. 12 , 1855-1874, (2006)

安全信息

WGK Germany3
Hazard statements
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
GHS Symbol
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. PyBOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶
  1. Pybox
  2. Nitrogen
  1. Ligands
  2. Nitrogen
  1. Pincer Ligands and Complexes
  2. Nitrogen

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