2-Fluoro-4-Methylphenylboronic Acid 2-氟-4-甲基苯硼酸
CAS 170981-26-7 MFCD05664239
化学结构图
SMILES: CC1C=CC(B(O)O)=C(F)C=1
化学属性
| Mol. Formula | C7H8BFO2 |
|---|---|
| Mol. Weight | 154 |
| Melting Point | 228-233 |
| TSCA | No |
| Density | 1.2 |
别名和识别编码
| Chemical Name | 2-Fluoro-4-Methylphenylboronic Acid |
|---|---|
| CAS Number | 170981-26-7 |
| Alfabeta Name | FLUOROMETHYLPHENYLBORONICACID 24--- |
| MDL Number | MFCD05664239 |
| Synonym | 2-FLUORO-4-METHYLBENZENEBORONIC ACID Boronic acid, (2-fluoro-4-methylphenyl)- (9CI) 2-FLUORO-4-METHYLPHENYLBORONIC ACID 4-Methyl-2-fluorophenylboronic acid (2-Fluoro-4-methylphenyl)boronic Acid 2-氟-4-甲基苯硼酸 4-Methyl-2-fluorophenylboronic Acid 2-氟-4-甲基苯基硼酸 2-Fluoro-4-methylphenylboronic acid ,97% 2-Fluoro-4-methylphenylboronic acid 2-Fluoro-4-Methylphenylboronic 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) |
| PubChem Substance ID | 87560954 |
| Reaxys-RN | 10427096 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 2-氟-4-甲基苯硼酸 |
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分类
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
- {SA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. Chai, D. I.; Lautens, M., Tandem Pd-Catalyzed Double C-C Bond Formation: Effect of Water J. Org. Chem. 74 , 3054-3061, (2009)
安全信息
- H315 Causes skin irritation 会刺激皮肤
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- P302+P352+P332+P313+P362+P364
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
其他信息
- MOL 文件:170981-26-7.mol
- Sigma Aldrich:170981-26-7(sigmaaldrich)
- 2-氟-4-甲基苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 F0683 2-氟-4-甲基苯硼酸(含有数量不等的酸酐) 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 5G 1870元 2011/04/16 F0683 2-氟-4-甲基苯硼酸(含有数量不等的酸酐) 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 1G 623元
- Hazard Note:Irritant
- 存储注意事项:氮气保护
- 上游原料:四氢呋喃 --> 正丁基锂 --> 硼酸三异丙酯 --> 4-溴-3-氟甲苯
- 检测方法:HPLC,NMR
