(Iodomethyl)triphenylphosphonium iodide 碘甲基-三苯基-碘化磷
CAS 3020-28-8 MFCD03931274
化学结构图
SMILES: IC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[I-]
化学属性
| Mol. Formula | C19H17I2P |
|---|---|
| Mol. Weight | 530 |
| Melting Point | 260-266 °C |
别名和识别编码
| Chemical Name | (Iodomethyl)triphenylphosphonium iodide |
|---|---|
| Synonym | (碘甲基)三苯基碘化膦 NSC 116665 |
| MDL Number | MFCD03931274 |
| CAS Number | 3020-28-8 |
| Chemical Name Translation | 碘甲基-三苯基-碘化磷 |
| PubChem Substance ID | 10973449 |
| InChI | InChI=1S/C19H17IP.HI/c20-16-21(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19;/h1-15H,16H2;1H/q+1;/p-1 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. C. Lichtenberg, et al., Eur. J. Inorg. Chem. 20 , 3117-3124, (2010)
- 2. Y. Bolshan and R. A. Batey, Tetrahedron 66 , 5283-5294, (2010)
- 3. M. Toumi, et al., Eur. J. Org. Chem. 20 , 3368-3386, (2009)
- 4. M. Beshai, et al., Tetrahedron Lett. 49 , 6794-6796, (2008)
- 5. N. Tseng and M. Lautens, J. Org. Chem. 74 , 2521-2526, (2009)
- 6. L. M. Bishop, et al., Angew. Chem. Int. Ed. Engl. 47 , 8100-8103, (2008)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
