(S)-(+)-4,12-Bis(di-3,5-Xylylphosphino)[2.2]Paracyclophane, Cth-(S)-3,5-Xylyl-Phanephos (S)-(+)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷
CAS 325168-88-5 MFCD03840578
化学结构图
SMILES: CC1=CC(C)=CC(=C1)P(C1C=C2CCC3C=CC(CCC=1C=C2)=CC=3P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1
化学属性
| Mol. Formula | C48H50P2 |
|---|---|
| Mol. Weight | 688.86 |
| Melting Point | 234-238 °C |
| TSCA | No |
| Appearance | white pwdr. |
别名和识别编码
| Chemical Name | (S)-(+)-4,12-Bis(di-3,5-Xylylphosphino)[2.2]Paracyclophane, Cth-(S)-3,5-Xylyl-Phanephos |
|---|---|
| Synonym | (S)-xylyl-PHANEPHos (S)-5,11-双(3,5-二甲苯基膦)三环[8.2.24,7]十六-己烯 (R)-Xylyl-PHANEPhos (R)-5,11-双(3,5-二甲苯基膦)三环[8.2.2.24,7]十六-己烯 (R)-(–)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷 (S)-xylyl-PHANEPHos (S)-5,11-双(3,5-二甲苯基膦)三环[8.2.24,7]十六-己烯 (S)-(+)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷 |
| MDL Number | MFCD03840578 |
| PubChem Substance ID | 329760782 |
| CAS Number | 325168-88-5 |
| Chemical Name Translation | (S)-(+)-4,12-双[二(3,5-二甲苯基)膦]-[2.2]-对环芳烷 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands, Privileged Ligands and Complexes
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, P-Phos, PhanePhos and BoPhoz Ligands, Privileged Ligands and Complexes
相关文献及参考
- 1. J. Am. Chem. Soc. 119 , 6207, (1997)
- 2. Org. Lett. 2 , 4173, (2000) 摘要
安全信息
GHS Symbol
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
