Grubbs Catalyst 2ND Generation Grubbs2代催化剂
CAS 246047-72-3 MFCD03453237
化学结构图
SMILES: C1CCC(P(C2CCCCC2)C2CCCCC2)CC1.Cc1cc(C)c(N2CCN(c3c(C)cc(C)cc3C)C2=[Ru](Cl)(Cl)=Cc2ccccc2)c(C)c1
化学属性
| Mol. Formula | C46H65Cl2N2PRu |
|---|---|
| Mol. Weight | 848.97 |
| Melting Point | 143.5-148.5 °C(lit.) |
别名和识别编码
| Chemical Name | Grubbs Catalyst 2ND Generation |
|---|---|
| Synonym | (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌 (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) Grubbs Catalyst™ C848 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌;格拉布催化剂;Grubbs催化剂; 1,3-双(2,4,6-三甲基苯基)-2-(咪唑烷亚基)(二氯苯亚甲基)(三环己基膦)钌 Grubbs Catalyst™ C848 Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)(tricyclohexylphosphine)ruthenium(II) (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 苯亚甲基-1,3-双(2,4,6-三甲苯基)-2-(咪唑啉卡宾)(三环己基磷)二氯化钌 Grubbs 2 代催化剂 |
| MDL Number | MFCD03453237 |
| CAS Number | 246047-72-3 |
| Chemical Name Translation | Grubbs2代催化剂 |
| PubChem Substance ID | 11147261 |
| LabNetwork Molecule ID | LN00226943 |
| InChI | InChI=1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Grubbs Catalyst Technology for Olefin Metathesis by Aldrich, Materials Science, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization, Ruthenium Catalysts
- {SNA} Catalysis, Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Development Quantities for Research, Grubbs Catalyst Technology for Olefin Metathesis by Aldrich, Polymer Science, Reagents for Polymerization, Ring Opening Polymerization, Ruthenium Catalysts, 材料科学
- {SA} Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Ma
产品应用
- Grubbs第二代催化剂
- 和第一代催化剂相比更有活性，且具有更广泛的底物范围，包括对空间有要求或失活的烯烃，如1,1 - 二取代烯烃和α，β-不饱和羰基化合物
安全信息
GHS Symbol
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- H228 Flammable solid 易燃固体
- R11 Highly flammable 非常易燃
