Tris[N,N-bis(trimethylsilyl)amide]samarium(III) 三[N,N-双(三甲基硅烷)胺]钐(III)

CAS 35789-01-6 MFCD03427097

化学结构图

35789-01-6
SMILES: C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

化学属性

Mol. FormulaSm(N(Si(CH3)3)2)3
Mol. Weight631.51
Melting Point93-106 °C(lit.)

别名和识别编码

Chemical NameTris[N,N-bis(trimethylsilyl)amide]samarium(III)
Synonym 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium 三[N,N-双(三甲基硅烷)胺]钐(III)
CAS Number35789-01-6
PubChem Substance ID24879000
MDL NumberMFCD03427097
Chemical Name Translation三[N,N-双(三甲基硅烷)胺]钐(III)
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分类

  • {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Samarium, Vapor Deposition Precursors, 材料科学
  • {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Samarium, Vapor Deposition Precursors

相关文献及参考

  • 1. F. Zhou, et al., Organometallics 30 , 1283-1286, (2011)
  • 2. Q. Wang, et al., J. Organomet. Chem. 694 , 691-696, (2009)
  • 3. G. M. Miyake, et al., Dalton Trans. 39 , 6710-6718, (2010) 摘要
  • 4. C. Quinet, et al., Tetrahedron Lett. 49 , 5032-5035, (2008)
  • 5. J. K. Nelson, et al., Tetrahedron Lett. 49 , 3078-3082, (2008)
  • 6. X. Yu and T. J. Marks, Organometallics 26 , 365-376, (2007)

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,C
Hazard statements
  • H228 Flammable solid 易燃固体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors Packaged for Deposition Systems - Vapor Deposition Precursors
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Vapor Deposition Precursors - Micro/NanoElectronics
  4. CVD and ALD Precursors by Metal - Vapor Deposition Precursors
  5. Samarium - CVD and ALD Precursors by Metal
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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