Tris[N,N-Bis(Trimethylsilyl)Amide]Neodymium(Iii) 三［N,N-双（三甲基硅烷）胺］钕(III)
CAS 148274-47-9 MFCD03427089
化学结构图
SMILES: C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
化学属性
| Mol. Formula | Nd(N(Si(CH3)3)2)3 |
|---|---|
| Mol. Weight | 625.39 |
| Melting Point | 156-159 °C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Tris[N,N-Bis(Trimethylsilyl)Amide]Neodymium(Iii) |
|---|---|
| Synonym | Neodymium(III) tris[N,N-bis(trimethylsilyl)amide] 三[N,N-双(三甲基硅烷)胺]钕(III) 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt |
| CAS Number | 148274-47-9 |
| PubChem Substance ID | 24878980 |
| MDL Number | MFCD03427089 |
| Chemical Name Translation | 三［N,N-双（三甲基硅烷）胺］钕(III) |
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分类
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Neodymium, Vapor Deposition Precursors
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Neodymium, Vapor Deposition Precursors, 材料科学
- {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Neodymium, Vapor Deposition Precursors
相关文献及参考
- 1. Y. A. Efimova, et al., Russ. J. Gen. Chem. 79 , 1641-1644, (2009)
- 2. M. Veith, et al., Eur. J. Inorg. Chem. 6 , 879-889, (2010)
- 3. H. F. Yuen and T. J. Marks, Organometallics 28 , 2423-2440, (2009)
- 4. H. He, et al., Aust. J. Chem. 57 , 803-810, (2004)
- 5. A. Fischbach, et al., Organometallics 25 , 1626-1642, (2006)
- 6. P. L. Arnold and S. T. Liddle, Chem. Commun. 45 , 5638-5640, (2005)
安全信息
GHS Symbol
- H228 Flammable solid 易燃固体
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R11 Highly flammable 非常易燃
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R34 Causes burns 会导致灼伤
