(R)-1,4-Dioxaspiro[4.5]Decane-2-Carbaldehyde (R)-1,4-二氧杂螺[4,5]癸烷-2-甲醛
CAS 78008-36-3 MFCD03093997
化学结构图
SMILES: O=C[C@H]1COC2(CCCCC2)O1
化学属性
| Mol. Formula | C9H14O3 |
|---|---|
| Mol. Weight | 170.21 |
| Density | 1.108 g/mL at 25 °C(lit.) |
| Refractive index | 1.4670 to 1.4710 |
| Boiling Point | 94°C/2mmHg(lit.) |
别名和识别编码
| Chemical Name | (R)-1,4-Dioxaspiro[4.5]Decane-2-Carbaldehyde |
|---|---|
| Synonym | (R)-1,4-二氧杂螺[4.5]癸烷-2-甲醛 (R)-2,3-Cyclohexylideneglyceraldehyde (R)-Cyclohexylideneglyceraldehyde 2,3-O-Cyclohexylidene-D-glyceraldehyde O,O-Cyclohexylidene-(R)-glyceraldehyde O,O-Cyclohexylidene-(R)-glyceraldehyde (R)-2,3-Cyclohexylideneglyceraldehyde 2,3-O-Cyclohexylidene-D-glyceraldehyde (R)-Cyclohexylideneglyceraldehyde |
| MDL Number | MFCD03093997 |
| PubChem Substance ID | 24878656 |
| CAS Number | 78008-36-3 |
| Chemical Name Translation | (R)-1,4-二氧杂螺[4,5]癸烷-2-甲醛 |
| Reaxys-RN | 3540045 |
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分类
- {SNA} Aldehydes, Asymmetric Synthesis, Building Blocks, C9, Carbonyl Compounds, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks
- Aldehydes, Asymmetric Synthesis, Building Blocks, C9, Carbonyl Compounds,
相关文献及参考
- 1. Ramachary, D. B.; et al., Design, synthesis and biological evaluation of optically pure functionalized spiro[5,5]undecane-1,5,9-triones as HIV-1 inhibitors Org. Biomolecular Chem. 9 , 7282-7286, (2011)
- 2. Kulkarni, M. G.; et al., A stereodivergent approach to carbahexofuranoses: Synthesis of carba-α-D-glucofuranose, carba-β-D-altrofuranose, carba-α-D-allofuranose, carba-β-D-idofuranose, carba-α-D-galactofuranose and carba-β-D-talofuranose Tetrahedron Lett. 52 , 5559-5562, (2011)
- 3. Kumar, C. N. S. S. P.; et al., Stereoselective synthesis of stagonolide G from D-mannitol Synthesis , 451-458, (2011)
- 4. Chattopadhyay, A.; et al., Crotylation of (R)-2,3-O-cyclohexylideneglyceraldehyde: a simple synthesis of (+)-trans-oak lactone Tetrahedron Lett. 51 , 3893-3896, (2010)
- 5. Venkataiah, M.; et al., Asymmetric synthesis of Goniothalesdiol A from (R)-2,3-O-cyclohexylidene glyceraldehyde Tetrahedron Asymmetry 20 , 2230-2233, (2009)
- 6. J. Org. Chem. 60 , 585-587, (1995)
- Biswas, S.; et al., A chemoenzymatic asymmetric synthesis of the hydroxy acid segment of schulzeines B and C Tetrahedron Asymmetry 21 , 27-32, (2010)
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
