(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride (1R,2R)-(-)-[1,2-环己二氨-N,N'-双(3,5-二叔丁基水杨基)]氯化铬

CAS 164931-83-3 MFCD02683488

化学结构图

164931-83-3
SMILES: CC(C)(C)C1=CC(=C(O)C(/C=N/[C@@H]2CCCC[C@H]2/N=C/C2C=C(C=C(C=2O)C(C)(C)C)C(C)(C)C)=C1)C(C)(C)C.Cl[Cr](Cl)Cl

化学属性

Mol. FormulaC36H52ClCrN2O2
Mol. Weight632.26
Melting Point>;350 °C(lit.)
Appearance brown pwdr.
RedoxReduction

别名和识别编码

Chemical Name(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride
Chemical Name Translation(1R,2R)-(-)-[1,2-环己二氨-N,N'-双(3,5-二叔丁基水杨基)]氯化铬
Synonym (R,R)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化铬(III)
MDL NumberMFCD02684555
PubChem Substance ID24877848
CAS Number164931-83-3
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cycloaddition, Privileged Ligands and Complexes, SALENs

安全信息

Hazard Codes Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Jacobsen Ligand
  2. Chromium
  1. Catalysts
  2. Chromium

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