2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 2-羟基苯硼酸频哪醇酯
CAS 269409-97-4 MFCD02093754
化学结构图
SMILES: CC1(C)OB(OC1(C)C)C1=CC=CC=C1O
化学属性
| Mol. Formula | C12H17BO3 |
|---|---|
| Mol. Weight | 220.08 |
| Density | 1.05 |
| Boiling Point | 282 |
| Refractive index | 1.5030 to 1.5080 |
| Appearance | pale yellow liq. |
别名和识别编码
| Chemical Name | 2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL |
|---|---|
| Synonym | 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 2-(4,4,5,5-四甲基-1,3,2-二杂氧戊硼烷-2-基)苯酚 2-羟基苯硼酸频哪醇酯 |
| MDL Number | MFCD02093754 |
| PubChem Substance ID | 87577653 |
| CAS Number | 269409-97-4 |
| Reaxys-RN | 9483037 |
| Chemical Name Translation | 2-羟基苯硼酸频哪醇酯 |
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分类
- Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
- {SNA} Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
相关文献及参考
- 1. X. Zheng, et al., , Syntheses and initial evaluation of a series of indolo-fused heterocyclic inhibitors of the polymerase enzyme (NS5B) of the hepatitis C virus Bioorg. Med. Chem. Lett. 21 , 2925-2929, (2011)
- 2. D. Gonzalez-Rodriguez, et al., , Activating multistep charge-transfer processes in fullerene-subphthalocyanine-ferrocene molecular hybrids as a function of p-p orbital overlap J. Am. Chem. Soc. 132 , 16488-16500, (2010)
- 3. D. Gonzalez-Rodriguez, et al., , Self-Assembled Monolayers of Subphthalocyanines on Gold Substrates Org. Lett. 12 , 2970-2973, (2010)
- 4. P. W. Ondachi and D. L. Comins,, Synthesis of Fused-Ring Nicotine Derivatives from (S)-Nicotine J. Org. Chem. 75 , 1706-1716, (2010)
- 5. S. Ishikawa and K. Manabe, , Synthesis of hydroxylated oligoarene-type phosphines by a repetitive two-step method Tetrahedron 66 , 297-303, (2010)
- 6. Tetrahedron 58 , 9633-9695, (2002)
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
