1-Fluoro-4-Hydroxy-1,4-Diazoniabicyclo[2.2.2]Octane Bis（(Tetrafluoroborate） 1-氟-4-羟基-1,4-重氮化二环2.2.2辛烷双（四氟硼酸盐）
CAS 162241-33-0 MFCD00467883
化学结构图
SMILES: O[N+]12CC[N+](F)(CC1)CC2.F[B-](F)(F)F.F[B-](F)(F)F
化学属性
| Mol. Formula | C6H13B2F9N2O |
|---|---|
| Mol. Weight | 322 |
| TSCA | No |
别名和识别编码
| Chemical Name | 1-Fluoro-4-Hydroxy-1,4-Diazoniabicyclo[2.2.2]Octane Bis（(Tetrafluoroborate） |
|---|---|
| MDL Number | MFCD00467883 |
| Synonym | Accufluor NFTh Accufluor™ NFTh Accufluor™ AccuFluor NFTh 氧化铝负载的 1-氟-4-羟基-1,4-重氮双环[2,2,2]辛烷双(四氟硼酸盐) |
| EC Number | 418-330-2 |
| CAS Number | 162241-33-0 |
| Beilstein Registry Number | 8369351 |
| PubChem Substance ID | 24870642 |
| Chemical Name Translation | 1-氟-4-羟基-1,4-重氮化二环2.2.2辛烷双（四氟硼酸盐） |
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分类
- {SNA} Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents
- {SNA} Alphabetic, Analytical Standards, Analytical/Chromatography, Chemical Synthesis, F, FA - FL, Fluorination, Fluorination Reagents, Synthetic Reagents
相关文献及参考
- AccuFluor is a registered trademark of AlliedSignal Inc.
- Versatile, reactive electrophilic fluorinating agent which can be used in water or organic solvents. A variety of substrates such as ketones: Tetrahedron Lett., 37, 3591 (1996), aromatics and enol ethers or enol esters, including steroidal derivatives, can be fluorinated successfully under mild conditions: Tetrahedron Lett., 40, 2673 (1999):
- Active methylene compounds (ß-diketonesandß-keto esters) are fluorinated in good yield in the presence of zinc chloride and imidazole or collidine. In the presence of water or alcohols, alkenes undergo hydroxy- or alkoxyfluorination to give fluorohydrin derivatives: Tetrahedron Lett., 36, 6769 (1995); 40, 2673 (1999).
安全信息
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S22 Do not breathe dust 不要吸入粉尘；
- R51/53
- R48/22
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R22 Harmful if swallowed 吞咽有害
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R50/53
GHS Symbol
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H318 Causes serious eye damage 严重伤害眼睛
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
