[(S,S)-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(IV) (S)-1,1'-binaphthyl-2,2'-diolate [(S,S)-乙烯二(4,5,6,7-四氢-1-茚基)]钛(IV) (S)-1,1′-联萘基-2,2′-二醇酸

CAS 83417-93-0 MFCD01863624

化学结构图

83417-93-0
SMILES: C1C[C@@]2(C=CC3CCCCC2=3)[Ti]2(OC3=CC=C4C=CC=CC4=C3C3C4C=CC=CC=4C=CC=3O2)[C@@]21C=CC1CCCCC2=1

化学属性

Mol. FormulaC40H38O2Ti
Mol. Weight598.60
Melting Point245 °C (dec.)(lit.)

别名和识别编码

Chemical Name[(S,S)-Ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(IV) (S)-1,1'-binaphthyl-2,2'-diolate
MDL NumberMFCD01863624
Synonym [(S,S)-乙烯二(4,5,6,7-四氢-1-茚基)]钛(IV) (S)-1,1′-联萘基-2,2′-二醇酸
Chemical Name Translation[(S,S)-乙烯二(4,5,6,7-四氢-1-茚基)]钛(IV) (S)-1,1′-联萘基-2,2′-二醇酸
PubChem Substance ID329757523
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Catalysts

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Catalysts - Chiral Catalysts, Ligands, and Reagents

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