(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) 环己二胺双(二叔丁基水杨烯)钴
CAS 188264-84-8 MFCD01631278
化学结构图
SMILES: CC(C)(C)C1=CC(=CC2C=N[C@H]3CCCC[C@@H]3N=CC3C=C(C=C(C=3O[Co]OC=21)C(C)(C)C)C(C)(C)C)C(C)(C)C |c:6,21,23,t:4,9,18|
化学属性
| Mol. Formula | [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co |
|---|---|
| Mol. Weight | 603.74 |
| Melting Point | >;350 °C (lit.) |
| Appearance | red-brown pwdr. |
别名和识别编码
| Chemical Name | (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) |
|---|---|
| MDL Number | MFCD01631278 |
| PubChem Substance ID | 24871025 |
| CAS Number | 188264-84-8 |
| Chemical Name Translation | 环己二胺双(二叔丁基水杨烯)钴 |
| Synonym | (S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II) |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Kinetic Resolution, Privileged Ligands and Complexes, SALENs
- {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Kinetic Resolution, Privileged Ligands and Complexes, SALENs
相关文献及参考
- 1. Tokunaga, M. et al. Science 277 , 936, (1997) 摘要
- 2. Jacobsen, E.N. et al. Tetrahedron Lett. 38 , 773, (1997)
安全信息
GHS Symbol
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- H311 Toxic in contact with skin 皮肤接触中毒
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
