1,1'-Bis(di-t-butylphosphino)ferrocene 1,1’-双(二叔丁基膦)二茂铁
CAS 84680-95-5 MFCD01630818
化学结构图
SMILES: CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[Fe]
化学属性
| Mol. Formula | C26H44FeP2 |
|---|---|
| Mol. Weight | 474.42 |
| Melting Point | 73-75 °C |
| TSCA | No |
| Refractive index | 熔点Melting point |
| Appearance | orange to red xtl. |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | 1,1’-双(二叔丁基膦)二茂铁 |
|---|---|
| Synonym | 1,1′-双(二叔丁基膦)二茂铁 1,1′-双(二叔丁基膦)二茂铁 DBtPF 1,1'-双(二-叔丁基膦基)二茂铁 |
| MDL Number | MFCD01630818 |
| CAS Number | 84680-95-5 |
| PubChem Substance ID | 329761720 |
| Chemical Name Translation | 1,1’-双(二叔丁基膦)二茂铁 |
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分类
- {SNA} Related Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Polydentate Phosphine Ligands
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Polydentate Phosphine Ligands
- {SNA} Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Polydentate Phosphine Ligands, Related Palladacycles
产品应用
- 形成二烯络合;羰基插入;加成;还原和脱氧反应。配体芳基化反应、Buchwald-Hartwig 交叉偶联反应、吲哚构成反应和Suzuki-Miyaura偶联反应的 配体
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
