(+)-Diisopinocampheyl Chloroborane (+)-二异松蒎基氯硼烷

CAS 112246-73-8 MFCD00074808

化学结构图

112246-73-8
SMILES: C[C@@H]1[C@@H](B(Cl)[C@H]2C[C@@H]3C[C@H]([C@@H]2C)C3(C)C)C[C@@H]2C[C@H]1C2(C)C

化学属性

Mol. FormulaC20H34BCl
Mol. Weight320.75
Density0.90
Flash Point110°C
Melting Point53-55°C
Boiling Point369.6±25.0 °C at 760 mmHg

别名和识别编码

Chemical Name(+)-Diisopinocampheyl Chloroborane
MDL NumberMFCD01317328
CAS Number112246-73-8
EC Number250-023-7
Beilstein Registry Number2384789
Reaxys-RN13205713
PubChem Substance ID13515837
Chemical Name Translation(+)-二异松蒎基氯硼烷
Synonym (+)-B-Chlorodiisopinocampheylborane {LY} (+)-B-Chlorodiisopinocampheylborane {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (+)-B-Chlorodiisopinocampheylborane {} {} {} {} {} {} {} {}
InChIInChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13-,14-,15+,16+,17-,18-/m0/s1
LabNetwork Molecule IDLN01745777
Canonical SMILESCC1(C)[C@@]2([H])C[C@H](B(Cl)[C@@H]3[C@@H](C)[C@@](C4)([H])C(C)(C)[C@@]4([H])C3)[C@@H](C)[C@]1([H])C2
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

安全信息

Signal word
GHS Symbol
WGK Germany3
Safety Statements
Risk Statements
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P403+P233
  • P305+P351+P338+P310
Packing GroupII
Storage condition -20°C {LY} -20°C 0-10 0-10°C 2-8°C 2-8℃保存 {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Hazard Codes
Hazard Class3/8

其他信息

  • Sigma Aldrich:112246-73-8(sigmaaldrich)
  • MOL 文件:112246-73-8.mol
  • 和水剧烈反应
  • (+)-二异松蒎基氯硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1614 (+)-B-二异松蒎基氯硼烷(58%的己烷溶液,约1.6mol/L) (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L) 100ML 2570元 2010/06/21 388428000 (+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane , 1.8M solution in hexanes, AcroSeal® 800 ML 20648元 2010/06/21 388421000 (+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane , 1.8M solution in hexanes, AcroSeal® 100 ML 6938元
  • 稳定性:(+)-二异松蒎基氯硼烷(112246-73-8)对水较敏感, 极易与空气中或溶剂中的水分反映生成氯化氢。受到空气中氧气氧化作用使其对酮的还原性降低。
  • TCI Shanghai:(+)-二异松蒎基氯硼烷(58%的正己烷溶液,约1.6mol/L) (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L)(112246-73-8)
  • 用途一:(+)-二异松蒎基氯硼烷(112246-73-8) are used for high enantiselective asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
  • F:10-21
  • 外观:无色透明液体
  • Acros Organics:(+)-二异松蒎基氯硼烷 (+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes, AcroSeal?(112246-73-8)
  • Alfa Aesar:(+)-DIP chloride, 97%(112246-73-8)

系列性分类


相关产品推荐