4-Amino-1-Boc-piperidine 1-Boc-4-氨基哌啶

CAS 87120-72-7 MFCD01076201

化学结构图

87120-72-7
SMILES: CC(C)(C)OC(=O)N1CCC(N)CC1

化学属性

Mol. FormulaC10H20N2O2
Mol. Weight200.28
Boiling Point80 °C at 0.037 mmHg
Melting Point50°C
TSCANo
Density1.422

别名和识别编码

Chemical Name4-Amino-1-Boc-piperidine
CAS Number87120-72-7
Alfabeta NameBOCAMINOPIPERIDINE N14----
MDL NumberMFCD01076201
EC Number250-023-7
Beilstein Registry Number2384789
Synonym tert-Butyl 4-aminopiperidine-1-carboxylate {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-carboxylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl 4-aminopiperidine-1-car
PubChem Substance ID87560680
Reaxys-RN4405047
Chemical Name Translation1-Boc-4-氨基哌啶
Canonical SMILESO=C(OC(C)(C)C)N(CC1)CCC1N
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分类

  • {SNA} Building Blocks, C10, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines

产品应用

  • 用于通过伯胺与树脂结合二甲磺酸盐的直接环化,微波辅助固相合成 N-取代哌啶。

安全信息

Warnings AIR SENSITIVE, CORROSIVE
Signal word
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn
Packing GroupIII
UN Number UN3259
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored un

系列性分类