1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate 1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)三氟甲磺酸铑(I)
CAS 136705-75-4 MFCD00269863
化学结构图
SMILES: [Rh+].C[C@H]1CC[C@H](C)P1C1C=CC=CC=1P1[C@@H](C)CC[C@@H]1C.[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1
化学属性
| Mol. Formula | C27H40F3O3P2RhS |
|---|---|
| Mol. Weight | 666.52 |
| Melting Point | 136.0-154.7 °C |
| Appearance | orange xtl. |
| Stability | air sensitive, store cold |
别名和识别编码
| Chemical Name | 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate |
|---|---|
| MDL Number | MFCD00269863 |
| CAS Number | 136705-75-4 |
| Synonym | 1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)三氟甲磺酸铑(I) |
| Chemical Name Translation | 1,2-双[(2S,5S)-2,5-二甲基磷]苯(环辛二烯)三氟甲磺酸铑(I) |
| PubChem Substance ID | 329760615 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
