1-Boc-Pyrrolidine 1-Boc-四氢吡咯

CAS 86953-79-9 MFCD00216581

化学结构图

86953-79-9
SMILES: CC(C)(C)OC(=O)n1cccc1

化学属性

Mol. FormulaC9H17NO2
Mol. Weight171.24
Density0.977
Refractive index1.4480 to 1.4520
Flash Point86°C(lit.)
TSCANo
Boiling Point80

别名和识别编码

Chemical Name1-Boc-Pyrrolidine
CAS Number86953-79-9
Alfabeta NameBUTYLPYRROLIDINECARBOXYLATE TERT1---
MDL NumberMFCD00216581
Synonym 1-(tert-Butoxycarbonyl)pyrrolidine 1-(tert-Butoxycarbonyl)pyrrolidinetert-Butyl pyrrolidine-1-carboxylate N-tert-Butoxycarbonylpyrrolidine tert-Butyl 1-Pyrrolidinecarboxylate tert-Butyl 1-Pyrrolidinecarboxylate, N-Boc-pyrrolidine
Beilstein Registry Number4664750
PubChem Substance ID253659760
Chemical Name Translation1-Boc-四氢吡咯
Reaxys-RN4664750
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分类

  • Intermediates
  • Heterocycles
  • Miscellaneous Reagents
  • {SNA} Building Blocks, C9 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Pyrrolidines

产品应用

  • N-Boc-pyrrolidine is a boc-protected cyclic amine used as a building block in the preparation of diastereomers by usually undergoing ?'-lithiations and electrophilic substitution reactions.

相关文献及参考

  • Beak, P. et al.: J. Org. Chem., 58, 1109 (1993);

安全信息

Warnings IRRITANT
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
GHS Symbol
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Hazard Codes Xi
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类