(1S,4R)-2-Azabicyclo[2.2.1]Hept-5-En-3-One (1S,4R)-2-氮杂双环[2.2.1]庚-5-烯-3-酮
CAS 130931-83-8 MFCD00211275
化学结构图
SMILES: O=C1N[C@@H]2C=C[C@H]1C2
化学属性
| Mol. Formula | C6H7NO |
|---|---|
| Mol. Weight | 109.13 |
| Melting Point | 94-97 °C(lit.) |
别名和识别编码
| Chemical Name | (1S,4R)-2-Azabicyclo[2.2.1]Hept-5-En-3-One |
|---|---|
| CAS Number | 130931-83-8 |
| Alfabeta Name | AZABICYCLOHEPTENONE RS14322152..[]()------, |
| MDL Number | MFCD00211275 |
| PubChem Substance ID | 24867650 |
| Chemical Name Translation | (1S,4R)-2-氮杂双环[2.2.1]庚-5-烯-3-酮 |
| Synonym | (1S)-(+)-2-氮杂双环[2.2.1]庚-5-烯-3-酮 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Lactams, Organic Building Blocks
相关文献及参考
- Evans, C.T. et al. J. Chem. Soc. Perkin Trans. I , 589, (1992)
- Campbell, J.A. et al. J. Org. Chem. 60 , 4602, (1995)
- Handa, S. et al. J. Chem. Soc. Perkin Trans. I , 1885, (1994)
- White, E.L. et al. Biochem. Biophys. Res. Commun. 161 , 393, (1989) 摘要
- Vince, R. Hua, M. J. Med. Chem. 33 , 17, (1990) 摘要
- Jung. M.E. Rhee, H. J. Org. Chem. 59 , 4719, (1994)
- FT-IR 2 (1), 1289:B / Structure Index 1 , 138:B:3
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
