(S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde (S)-(-)-3-(叔丁氧羰基)-4-甲酰-2,2-二甲基-1,3-噁唑烷
CAS 102308-32-7 MFCD00209557
化学结构图
SMILES: CC(C)(C)OC(=O)N1[C@@H](COC1(C)C)C=O
化学属性
| Mol. Formula | C11 |
|---|---|
| Mol. Weight | 229 |
| Refractive index | 1.4450 to 1.4470 |
| Boiling Point | 97°C/1.5mmHg(lit.) |
| Density | 1.06 |
| TSCA | No |
| Flash Point | 107°C(lit.) |
别名和识别编码
| Chemical Name | (S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde |
|---|---|
| Synonym | (S)-(-)-3-Boc-2,2-二甲基噁唑烷-4-甲醛 (-)-N-Boc-N,O-异亚丙基-L-丝氨醛 (-)-N-Boc-N,O-异亚丙基-L-丝氨醛 (S)-(-)-4-甲酰基-2,2-二甲基-3-噁唑啉羧酸叔丁酯 Garner 醛 (S)-(-)-3-tert-Butoxycarbonyl-2,2-dimethyloxazolidine-4-carboxaldehyde (S)-(-)-4-甲酰基-2,2-二甲基-3-噁唑啉羧酸叔丁酯 |
| CAS Number | 102308-32-7 |
| PubChem Substance ID | 87564654 |
| Beilstein Registry Number | 3591324 |
| MDL Number | MFCD00209557 |
| Reaxys-RN | 3591324 |
| Merck Number | 14,4371 |
| Chemical Name Translation | (S)-(-)-3-(叔丁氧羰基)-4-甲酰-2,2-二甲基-1,3-噁唑烷 |
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分类
- {SNA} Aldehydes, Asymmetric Synthesis, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Synthesis, Chiral Auxiliaries, Organic Building Blocks, Oxazolidinone Derivatives
- Aldehydes, Asymmetric Synthesis, Building Blocks, C10-C12, Carbonyl Compounds, Chemical Synthesis, Chiral Auxiliaries, Organic Building Blocks, Oxazolidinone Derivatives
相关文献及参考
- 1. Hoemann, M.Z. et al. Tetrahedron Lett. 37 , 953, (1996)
- 2. Roush, W.R. Hunt, J.A. J. Org. Chem. 60 , 798, (1995)
- 3. Guibourdenche, C. et al. Tetrahedron Asymmetry 4 , 2041, (1993)
- Merck 14 ,4371
- FT-IR 2 (1), 1307:A / Structure Index 1 , 140:C:3
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P302+P352+P332+P313+P362+P364
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
