Tetrabutylammonium Difluorotriphenylstannate(Iv) 四丁基二氟三苯基锡酸铵

CAS 139353-88-1 MFCD00192465

化学结构图

139353-88-1
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.F[Sn-](F)(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC34H51F2NSn
Mol. Weight630.50
Melting Point191.0 to 195.0 deg-C
TSCANo

别名和识别编码

Chemical NameTetrabutylammonium Difluorotriphenylstannate(Iv)
CAS Number139353-88-1
Alfabeta NameTETRABUTYLAMMONIUMDIFLUOROTRIPHENYLSTANNATE
MDL NumberMFCD00192465
Synonym Gingras' Reagent 四丁基二氟三苯基锡酸铵 Tetrabutylammonium difluorotriphenyltin
Beilstein Registry Number8668854
EC Number000-000-0
PubChem Substance ID87577349
Reaxys-RN8668854
Chemical Name Translation四丁基二氟三苯基锡酸铵
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis, Fluorination, Fluorination Reagents, Phase Transfer Catalysts, Synthetic Reagents

相关文献及参考

  • Can be regarded as a non-hygroscopic anhydrous equivalent of TBAF useful in the preparation of gem-difluorides: Synlett., 8, 587 (1993), and the alkylation of enol silyl ethers: Tetrahedron Lett., 32, 7381 (1991). For use in the fluorination of carbohydrates, see: Tetrahedron Asymmetry, 9, 213 (1998).

安全信息

Warnings IRRITANT
GHS Symbol
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P302+P350
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Packing GroupIII
UN Number 3146 UN3146
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R50/53
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Hygroscopic
Hazard Codes T,N
Hazard Class6.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorination Reagents 含氟试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Chlorination - C-X Bond Formation (Halogen)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Halogenation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物

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