2,2’-Methylenebis[(4S)-4-Phenyl-2-Oxazoline] 2,2’-亚甲基双[(4S)-4-苯基-2-噁唑啉]

CAS 132098-59-0 MFCD00192295

化学结构图

132098-59-0
SMILES: C(C1=N[C@H](CO1)C1C=CC=CC=1)C1=N[C@H](CO1)C1C=CC=CC=1

化学属性

Mol. FormulaC19H18N2O2
Mol. Weight306.36
Refractive indexn20/D 1.586(lit.)
Boiling Point131-134 °C/0.01 mmHg(lit.)
Density1.28 g/mL at 25 °C(lit.)

别名和识别编码

Chemical Name2,2’-Methylenebis[(4S)-4-Phenyl-2-Oxazoline]
Synonym 2,2′-亚甲基双[(4S)-4-苯基-2-噁唑啉] (S,S)-2,2′-亚甲基双(4-苯基-2-噁唑啉)
CAS Number132098-59-0
PubChem Substance ID24866074
Beilstein Registry Number4202633
MDL NumberMFCD00192295
Chemical Name Translation2,2’-亚甲基双[(4S)-4-苯基-2-噁唑啉]
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分类

  • Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Gant, T.G. Meyers, A.I. Tetrahedron 50 , 2297, (1994)
  • 2. Pfaltz, A. Acc. Chem. Res. 26 , 339, (1993)
  • 3. Bolm, C. Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)
  • FT-IR 2 (2), 2214:B / Structure Index 1 , 236:A:8

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes

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