(R,R)-2,2-(Dimethylmethylene)Bis(4-Phenyl-2-Oxazoline) (R,R)-2,2’-异丙亚基双(4-苯基-2-噁唑啉)

CAS 150529-93-4 MFCD00192244

化学结构图

150529-93-4
SMILES: CC(C)(C1=N[C@@H](CO1)C1C=CC=CC=1)C1=N[C@@H](CO1)C1C=CC=CC=1

化学属性

Mol. FormulaC21H22N2O2
Mol. Weight334
Melting Point56-58
Density1.18

别名和识别编码

Chemical Name(R,R)-2,2-(Dimethylmethylene)Bis(4-Phenyl-2-Oxazoline)
Synonym (+)-2,2′-异亚丙基双[(4R)-4-苯基-2-噁唑啉] (R,R)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane, (R,R)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline)
MDL NumberMFCD00192244
PubChem Substance ID87569212
Beilstein Registry Number4266906
CAS Number150529-93-4
Reaxys-RN7490868
Chemical Name Translation(R,R)-2,2’-异丙亚基双(4-苯基-2-噁唑啉)
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分类

  • Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Gant, T.G. Meyers, A.I. Tetrahedron 50 , 2297, (1994)
  • 2. Pfaltz, A. Acc. Chem. Res. 26 , 339, (1993)
  • 3. Bolm, C. Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)
  • FT-IR 2 (2), 2214:C / Structure Index 1 , 236:B:8

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P311
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H301+H311+H331
  • H330 Fatal if inhaled 吸入致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Hazard Codes 6.1 T
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
UN Number 2811
Packing GroupIII
Storage condition 0-10°C

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes

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