Ethyl 3-Oxo-4-(Triphenylphosphoranylidene)Butyrate 2-氧-4-(三苯基膦)丁酸乙酯
CAS 13148-05-5 MFCD00192162
化学结构图
SMILES: CCOC(=O)CC(=O)C=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | (C6H5)3P=CHCOCH2CO2C2H5 |
|---|---|
| Mol. Weight | 390 |
| Melting Point | 101-106 |
别名和识别编码
| Chemical Name | Ethyl 3-Oxo-4-(Triphenylphosphoranylidene)Butyrate |
|---|---|
| CAS Number | 13148-05-5 |
| Synonym | 4-(Triphenylphosphoranylidene)acetoacetic Acid Ethyl Ester 4-(Triphenylphosphoranylidene)acetoacetic acid ethyl ester [3-(Ethoxycarbonyl)-2-oxopropylidene]triphenylphosphorane 3-Oxo-4-(triphenylphosphoranylidene)butanoic Acid Ethyl Ester 3-Oxo-4-(triphenylphosphoranylidene)butanoic acid ethyl ester 3-Oxo-4-(triphenylphosphoranylidene)butanoic acid ethyl ester 4-(Triphenylphosphoranylidene)acetoacetic acid ethyl ester [3-(Ethoxycarbonyl)-2-oxopropylidene]triphenylphosphorane 2-氧-4-(三苯基膦)丁酸乙酯 |
| MDL Number | MFCD00192162 |
| PubChem Substance ID | 24866344 |
| Chemical Name Translation | 2-氧-4-(三苯基膦)丁酸乙酯 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
- Miscellaneous Reagents
产品应用
- A useful synthetic intermediate in the production of antibiotics.
相关文献及参考
- 1. Tetrahedron Lett. 34 , 4837, (1993)
- 2. Synthesis , 453, (1992)
- A. Ma, and D. Ma, Org. Lett. 12 , 3634-3637, (2010)
- K. Jiang, et al., Org. Lett. 12 , 2766-2769, (2010)
- Y. Liu, et al., Org. Lett. 11 , 2848-2851, (2009)
- U. Albrecht, et al., J. Org. Chem. 69 , 3417-3424, (2004)
- C. M. Moorhoff, J. Chin. Chem. Soc. 50 , 419-424, (2003)
- M. J. Ellis and M. F. G. Stevens, J. Chem. Res. Synop. 2 , 75-77, (2003)
- FT-IR 2 (2), 3342:C / Structure Index 1 , 357:E:4
安全信息
GHS Symbol
