(4-Ethoxy-2,4-Dioxobutyl)Triphenylphosphonium Chloride [3-(乙氧羰基)-2-氧丙基]三苯基氯化膦
CAS 106302-03-8 MFCD00192128
化学结构图
SMILES: [Cl-].CCOC(=O)CC(=O)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C2H5O2CCH2COCH2P(C6H5)3Cl |
|---|---|
| Mol. Weight | 426.87 |
| Melting Point | 160 °C (dec.)(lit.) |
别名和识别编码
| Chemical Name | (4-Ethoxy-2,4-Dioxobutyl)Triphenylphosphonium Chloride |
|---|---|
| MDL Number | MFCD00192128 |
| PubChem Substance ID | 24866559 |
| CAS Number | 106302-03-8 |
| Synonym | [3-(乙氧羰基)-2-丙氧基]三苯基氯化膦 |
| Chemical Name Translation | [3-(乙氧羰基)-2-氧丙基]三苯基氯化膦 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- FT-IR 2 (2), 3339:B / Structure Index 1 , 357:D:1
- 3. Davis, M.; Wu, W. Y. Aust. J. Chem. 41 , 1591, (1988)
- 1. Edwards, P. D.; et al. J. Med. Chem. 50 , 5912, (2007)
- 2. Hanold, N.; et al. Z. Naturforsch. B 50 , 1121, (1995)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
