2,2′-Bis[(4S)-4-benzyl-2-oxazoline] 2,2'-双((4S)-4-苄基-2-恶唑啉)

CAS 133463-88-4 MFCD00191793

化学结构图

133463-88-4
SMILES: C([C@@H]1COC(=N1)C1=N[C@H](CC2C=CC=CC=2)CO1)C1C=CC=CC=1 |&1:1,8|

化学属性

Mol. FormulaC20H20N2O2
Mol. Weight320.39
Melting Point129-132 °C(lit.)

别名和识别编码

Chemical Name2,2′-Bis[(4S)-4-benzyl-2-oxazoline]
Synonym 2,2′-双[(4S)-4-苄基-2-噁唑啉] (S,S)-2,2′-双(4-苄基-2-噁唑啉) (S,S)-2,2′-双(4-苄基-2-噁唑啉) (S,S)-4,4′-二苄基-2,2′-二(2-噁唑啉) (S,S)-4,4′-二苄基-2,2′-二(2-噁唑啉)
MDL NumberMFCD00191793
PubChem Substance ID24865344
Beilstein Registry Number4756827
CAS Number133463-88-4
Chemical Name Translation2,2'-双((4S)-4-苄基-2-恶唑啉)
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分类

  • Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Helmchen, G. et al. Synlett , 257, (1991)
  • Structure Index 1 , 236:D:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. imido ester

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