(3-Benzyloxypropyl)Triphenylphosphonium Bromide (3-苄氧基丙基)三苯基溴化鏻
CAS 54314-85-1 MFCD00191781
化学结构图
SMILES: [Br-].C(OCCC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C6H5CH2O(CH2)3P(C6H5)3Br |
|---|---|
| Mol. Weight | 491.40 |
| Melting Point | 153-154 °C(lit.) |
别名和识别编码
| Chemical Name | (3-Benzyloxypropyl)Triphenylphosphonium Bromide |
|---|---|
| MDL Number | MFCD00191781 |
| PubChem Substance ID | 24864267 |
| CAS Number | 54314-85-1 |
| Synonym | (3-苄氧基丙基)三苯基溴化鏻 |
| Chemical Name Translation | (3-苄氧基丙基)三苯基溴化鏻 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Nemoto, T.; et al. Org. Lett. 12 , 5020, (2010)
- 2. Shen, G.; et al. J. Org. Chem. 71 , 7618, (2006)
- 3. Lindsley, C. W.; et al. J. Am. Chem. Soc. 122 , 422, (2000)
- FT-IR 2 (2), 3336:A / RegBook 1 (2), 2277:I / Structure Index 1 , 356:D:6
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
