(Allyloxycarbonylmethyl)triphenylphosphonium iodide (烯丙氧基羰甲基)三苯基碘化膦

CAS 206557-04-2 MFCD00191712

化学结构图

206557-04-2
SMILES: [I-].C=CCOC(=O)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. Formula(C6H5)3P(CH2CO2CH2CH=CH2)I
Mol. Weight488.30
Melting Point138 °C (dec.)(lit.)

别名和识别编码

Chemical Name(Allyloxycarbonylmethyl)triphenylphosphonium iodide
MDL NumberMFCD00191712
PubChem Substance ID24864594
CAS Number206557-04-2
Synonym (烯丙氧基羰甲基)三苯基碘化膦
Chemical Name Translation(烯丙氧基羰甲基)三苯基碘化膦
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. J. Med. Chem. 34 , 2759, (1991) 摘要
  • FT-IR 2 (2), 3339:A / Structure Index 1 , 357:C:1

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类


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