O-(5-Norbornene-2,3-Dicarboximido)-N,N,N’,N’-Tetramethyluronium Tetrafluoroborate O-(5-降冰片烯基-2,3-二羰亚胺)-N,N,N’,N’-四甲基脲四氟硼酸盐

CAS 125700-73-4 MFCD00167753

化学结构图

125700-73-4
SMILES: CN(C)C(ON1C(=O)C2[C@@H]3C[C@@H](C=C3)C2C1=O)=[N+](C)C.F[B-](F)(F)F |&1:9,11|

化学属性

Mol. FormulaC14H20BF4N3O3
Mol. Weight365
Melting Point216-219
TSCANo
Density1.422
Stability对光敏感，对湿度敏感

别名和识别编码

Chemical NameO-(5-Norbornene-2,3-Dicarboximido)-N,N,N’,N’-Tetramethyluronium Tetrafluoroborate
Synonym 5-降冰片烯-2,3-二羰基-N,N,N',N'-四甲基脲四氟硼酸酯 5-降冰片烯-2,3-二羰基-N,N,N',N'-四甲基脲四氟硼酸酯 TNTU O-(5-降冰片烯基-2,3-二羰亚胺)-N,N,N′,N′-四甲基脲四氟硼酸盐 O-(Bicyclo[2.2.1]hept-5-ene-2,3-dicarboximido)-N,N,N′,N′-tetramethyluronium tetrafluoroborate TNTU
MDL NumberMFCD00167753
PubChem Substance ID87573948
CAS Number125700-73-4
Reaxys-RN4638320
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name TranslationO-(5-降冰片烯基-2,3-二羰亚胺)-N,N,N’,N’-四甲基脲四氟硼酸盐
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分类

  • {SNA} Alicyclic/Etch-Resistant Monomers, Chemical Biology, Chemical Synthesis, Coupling, Lithography Monomers, Micro/NanoElectronics, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Self Assembly & Contact Printing, Synthetic Reagents, 材料科学
  • {SNA} Alicyclic/Etch-Resistant Monomers, Chemical Biology, Chemical Synthesis, Coupling, Lithography Monomers, Materials Science, Micro/NanoElectronics, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Self Assembly & Contact Printing, Synthetic Reagents
  • {SNA} Alicyclic/Etch-Resistant Monomers,

相关文献及参考

  • FT-NMR 1 (1), 1302:C / RegBook 1 (1), 933:L / Structure Index 1 , 145:B:5

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes 8
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
UN Number 1759
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture & Light Sensitive 阴凉干燥处保存。
Packing GroupIII
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Coupling - Synthetic Reagents
  4. Phosphonium/Uronium/Formamidinium - Coupling
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Peptide Coupling - Peptide Chemistry
  5. Phosphonium/Uronium/Formamidinium - Peptide Coupling
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Condensation & Active Esterification
  1. Functional Group 官能团索引
  2. isourea
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Peptide Synthesis

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