5-Ethylidenebicyclo[2.2.1]Hept-2-Ene 5-亚乙基双环[2.2.1]庚烷-2-烯
CAS 16219-75-3 MFCD00167576
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 5ring; 6ring; racemate; 1fragment
- {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
- {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Materials Science, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science
- {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science, 材料科学
相关文献及参考
- Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
- Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P303+P361+P353
- P308+P313
- P301+P310
- P331 Do NOT induce vomiting.. 不要催吐。
- P273 Avoid release to the environment. 避免释放到环境中。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P337+P313
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
- R10 Flammable 易燃
- R20 Harmful by inhalation 吸入有害
{haz
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 2830 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 732 ppm/4H TOXIC EFFECTS : Behavioral - muscle weakness REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,250,1971
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 3104 ppm/4H TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - ulcerated nasal septum REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,250,1971
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Human DOSE/DURATION : 6 ppm/30M TOXIC EFFECTS : Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - conjunctive irritation Sense Organs and Special Senses (Taste) - change in function REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,250,1971
TYPE OF TEST
TYPE OF TEST : TCLo - Lowest published toxic concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE : 100 ppm/6H SEX/DURATION : female 6-15 day(s) after conception TOXIC EFFECTS : Reproductive - Maternal Effects - other effects Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : IOMTE3 International Journal of Occupational Medicine and Toxicology. (Princeton Scientific Publishing, POB 2155, Princeton, NJ 08543) V.3(2)- 4(4), 1994-95 Volume(issue)/page/year: 4,371,1995
其他信息
- 蒸气压:4.6 mm Hg ( 20 °C)
- Alfa Aesar:5-亚乙基-2-降冰片烯,endo+exo,98%,100ppm对叔丁基儿茶酚作稳定剂 5-Ethylidene-2-norbornene, endo + exo, 98%, stab. with 100ppm 4-tert-butylcatechol(16219-75-3)
- 图谱信息:乙叉降冰生烯(16219-75-3)质谱(MS) 乙叉降冰生烯(16219-75-3)Raman光谱 乙叉降冰生烯(16219-75-3)红外图谱(IR1)
- TCI Shanghai:5-乙叉-2-降冰片烯 5-Ethylidene-2-norbornene,>;98.0%(GC)(16219-75-3)
- 方法一:用环戊二烯(或双环戊二烯)和1,3-丁二烯经第尔斯-阿尔德(Diels-Alder)反应得到乙烯基降冰片烯,再经异构化反应生成亚乙基降冰片烯。另一种制备法是以丁二烯为原料,经氯化制得3-氯-1-丁烯,再与歪戊二烯加成得5-(1-氯乙基)-2-降冰片烯,最后用氧化钙脱去盐酸而得产品。
- Acros Organics:5-乙叉-2-降冰片烯 5-Ethylidene-2-norbornene, mixt. of endo- and exo-isomers, stabilized, 98+%(16219-75-3)
- 用途一:该品作为第三单体,与乙烯、丙烯共聚可得乙丙橡胶。秘得橡胶的硫化速度比其他第三单体快,可以克服乙丙乙丙橡胶硫化速度慢的缺点。它还具有耐臭氧、耐化学药品(溶剂、酸、碱等)、耐放电、耐水蒸气等性能。因此,可用作发动机周围的橡胶制品、防水板等建筑材料和耐冲击性塑料的改性材料。
- 乙叉降冰生烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0244 5-亚乙基-2-降冰片烯 5-Ethylidene-2-norbornene 25ML 154元 2014/06/02 E0244 5-亚乙基-2-降冰片烯 5-Ethylidene-2-norbornene 500ML 530元 2010/06/21 166010025 乙叉降冰生烯 5-Ethylidene-2-norbornene 98+%, mixt. of endo- and exo-isomers, stabilized 2.5 KG 2223元
- 上游原料:氧化钙 --> 1,3-丁二烯 --> 茂 --> 二聚环戊二烯 --> 降冰片烯 --> 3-氯-1-丁烯
- MOL 文件:16219-75-3.mol
- 蒸气密度:4.1 (vs air)
- Sigma Aldrich:16219-75-3(sigmaaldrich)