Copper(II) nitrate trihydrate 硝酸铜三水合物
CAS 10031-43-3 MFCD00149671
化学结构图
SMILES: O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Cu+2]
化学属性
| Mol. Formula | Cu(NO3)2·3H2O |
|---|---|
| Mol. Weight | 242 |
| Density | 2.561 |
| Melting Point | 114 |
| Solubility | 易溶于水、乙醇。 |
| TSCA | Yes |
| Boiling Point | 170° dec. |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Copper(II) nitrate trihydrate |
|---|---|
| MDL Number | MFCD00149671 |
| Synonym | Copper(II) nitrate trihydrate Cupric nitrate Cupric nitrate hemi(pentahydrate) Cupric nitrate 三水合物 三水 硝酸铜 硝酸铜 三水合物 |
| EC Number | 221-838-5 |
| CAS Number | 10031-43-3 |
| Merck Number | 14,2643 |
| PubChem Substance ID | 24882082 |
| Chemical Name Translation | 硝酸铜三水合物 |
| LabNetwork Molecule ID | LN00223832 |
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分类
- Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, C-D, Puriss p.a. ACS, Puriss p.a. ACS
产品应用
- 分析锶，芳香有机硅化合物硝化剂，有机反应催化剂。
相关文献及参考
- Has been used on clay support for aromatic nitrations, oxidative cleavage of thioacetals, and aromatization of dihydropyridines. For reviews, see: Synthesis, 909 (1985); Acc. Chem. Res., 19, 121 (1986).
- Reacts with H2O2 in the presence of KHCO3 to give CuO2H, stable at room temperature in the absence of moisture, a selective oxidant for the conversion of alcohols to aldehydes in high yield: Tetrahedron Lett., 31, 3891 (1990).
- For use in the coupling of vinyl stannanes, see: Tetrahedron Lett., 36, 197 (1995).
- Merck: 14,2643
安全信息
- S17 Keep away from combustible material 远离可燃物料；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R50/53
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
GHS Symbol
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H315 Causes skin irritation 会刺激皮肤
- H318 Causes serious eye damage 严重伤害眼睛
- H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
- H302 Harmful if swallowed 吞食有害
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P352
- P305+P351+P338
其他信息
- 有毒，具潮解性，易溶于水和醇，几乎不溶于乙酸乙酯，0.2M水溶液的pH值为4.0，170度分解放出氧，与炭末、硫磺或其他可燃性性质加热打击和摩擦时，发生有毒和刺激性的过氧化氮。
