Sodium molybdate dihydrate 钼酸钠二水合物

CAS 10102-40-6 MFCD00149170

化学结构图

10102-40-6
SMILES: O.O.[Na+].[Na+].[O-][Mo]([O-])(=O)=O

化学属性

Mol. FormulaNa2MoO4?2H2O
Mol. Weight242
Melting Point100
Density3.28
TSCANo
SolubilitySoluble in water
Appearance 白色菱形结晶。相对密度3.28。微溶于水,不溶于丙酮。加热到100℃失去结晶水变成无水物。有毒!
Stability易吸潮

别名和识别编码

Chemical NameSodium molybdate dihydrate
Synonym SODIUM MOLYBRATE Sodium molybdate, dihydrate 钼酸钠 二水 MOLYBDIC ACID SODIUM SALT: DIHYDRATE SODIUM MOLYBDATE DIHYDRATE, 99+%, A.C.S. REAGENT Molybdate (MoO42-), sodium, hydrate (1:2:2), (T-4)- SODIUM MOLYBDATE DIHYDRATE MOLYBDIC ACID SODIUM DIHYDRATE Molybdic acid sodium salt, dihydrate
MDL NumberMFCD00149170
EC Number231-551-7
CAS Number10102-40-6
Merck Number14,8645
PubChem Substance ID24896680
Chemical Name Translation钼酸钠二水合物
Wiswesser Line Notation.NA..MO-O4 &QH 2
LabNetwork Molecule IDLN02056052
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Molybdenum, Research Essentials, Salts, Sodium Salts
  • {SNA} Analytical Reagents for General Use, Essential Chemicals, Puriss p.a., Q-S, Puriss p.a., Research Essentials, Salts, Sodium Salts, 分析/色谱, 分析试剂
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Molybdenum, Molybdenum Salts, Research Essentials, Salts
  • {Chemicalbook} 无机化工产品: 无机盐: Cp钼、钛、钨、钒、锆
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Molybdenum
  • {SNA} ACS Grade,

产品应用

  • 用于制造生物碱、油墨、化肥、钼红颜料和耐晒颜料的沉淀剂、催化剂、钼盐,也可用于制造阻燃剂和无公害型冷水系统的金属抑制剂,还用作镀锌、磨光剂及化学试剂。

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSQA5085000
Hazard Codes Xi
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany1
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
GHS Symbol
Precautionary statements
Storage condition Store at RT. 易吸潮,密封保存
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 520 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - coma
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 154,243,1965

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 257 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - coma
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 154,243,1965

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 401 mg/kg
SEX/DURATION            : female 6 week(s) pre-mating
                          female 1-21 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - menstrual cycle changes or disorders
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   NTRSDC Nutrition Research.  (Pergamon Press Inc., Maxwell House, Fairview
   Park, Elmsford, NY 10523) V.1-   1981-  Volume(issue)/page/year: 10,515,1990

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 968 gm/kg
SEX/DURATION            : female 8 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 33,47,1984

其他信息

  • 下游产品:磷酸 --> 对溴甲苯 --> 乙酸钙
  • 微溶于水,不熔于丙酮。5%水溶液在25℃时,pH为9~10。比重3.28。100℃时失去结晶水而成为无水物。有毒。
  • MSDS 信息:Sodium molybdate dihydrate(10102-40-6).msds
  • 方法一:液碱萃取法钼精矿经氧化焙烧生成三氧化钼,再用液碱浸取,得到钼酸钠溶液,浸出液经抽滤、蒸发浓缩,浓缩液经冷却结晶、离心分离,在70~80℃温度下干燥,即得钼酸钠成品。其 2Mos2+7O2→2MoO3+4SO2↑ MoO3+2NaOH+H2O→Na2MoO4?2H2O
  • 海关编码:28417000
  • Alfa Aesar:钼酸钠二水合物,ACS,99.5-103.0% Sodium molybdenum oxide dihydrate, ACS, 99.5-103.0%(10102-40-6)
  • 用途二:用于制造生物碱、油墨、化肥、钼红颜料和耐晒颜料的沉淀剂、催化剂、钼盐,也可用于制造阻燃剂和无公害型冷水系统的金属抑制剂,还用作镀锌、磨光剂及化学试剂。
  • 钼酸钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10019818 钼酸钠;二水合钼酸钠;钼酸钠;二水 500g 185元 2010/06/21 206370050 钼酸钠 Sodium molybdate(VI) dihydrate 99+% 5 GR 367元 2010/06/21 206375000 钼酸钠 Sodium molybdate(VI) dihydrate 99+% 500 GR 1944元
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 44.1g/0℃;64.7g/10℃;65.3g/20℃;66.9g/30℃;68.6g/40℃ 71.8g/60℃
  • Acros Organics:二水钼酸钠 Sodium molybdate(VI) dihydrate, 99+%(10102-40-6)
  • Sigma Aldrich:10102-40-6(sigmaaldrich)
  • 参考质量标准:企业标准津Q/HG 1-966—82(1987年确认) 指标名称 指标 一级品 二级品 钼酸钠(Na2MoO4?2H2O)/%≥ 99 98
  • 上游原料:三氧化钼 --> 钼精矿
  • 图谱信息:钼酸钠(10102-40-6)红外图谱(IR1)
  • MOL 文件:10102-40-6.mol
  • 用途一:用于制造生物碱及其他物质的试剂,也用于染料、钼红颜料、催化剂、钼盐和耐晒色淀沉淀剂。是制造阻燃剂的原料和无公害型冷却水系统的金属腐蚀抑制剂,以及作为动植物必须的微量成分。
  • 毒性:参见三氧化钼。

系列性分类