Triphenylphosphine, polymer supported 1.4-2.0mmol/g on polystyrene 200-400 mesh 2% DVB loading 聚合物键合型三苯基膦
CAS 39319-11-4 MFCD00148025
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ligands, Phosphine Compounds, Phosphine Ligands, Solid Supported Synthesis, Specialty Synthesis, Supported Reagents
- {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Ligands, Phosphine Compounds, Phosphine Ligands,
相关文献及参考
- 1. Clark, H.C., et al. J. Organomet. Chem. 322 , 393, (1987)
- Bernard, M. et. al. J. Org. Chem. 48 , 326, (1983)
- Relles, H.M.; Schuenz, R.W. J. Am. Chem. Soc. 96 , 6469, (1974)
- Regen, S.L.; Lee, D.P. J. Am. Chem. Soc. 40 , 1669, (1975)
- Landi, J.J. Jr.;Brinkman, H.R. Synthesis , 1093, (1992)
- Support for nickel, rhenium and rhodium in hydrogenation: J. Am. Chem. Soc., 97, 1742 (1975); dimerization of alkenes: J. Am. Chem. Soc., 97, 341 (1974) and hydroformylation: J. Am. Chem. Soc., 98 5402 (1976). For the halogenation of carboxylic acid and alkanes in carbon tetrachloride: Synthesis, 1093 (1992). Addition of iodine in DMF esterifies primary and secondary alcohols to their respective formate esters: Med. Res. Rev., 19, 97 (1999).
- For use in the Mitsunobu reaction: Tetrahedron Lett., 8751 (1998), and the Wittig reaction: J. Org. Chem., 48, 326 (1983); J. Chem. Soc. Perkin 1, 2243 (1998).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S24 Avoid contact with skin 避免皮肤接触;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S37 Wear suitable gloves 戴适当手套;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害