异辛烷中丙体六六六溶液标准物质(0.1ug/ml) γ-六六六标准溶液
CAS 58-89-9 MFCD00135947
化学结构图
SMILES: Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl
化学属性
| Mol. Formula | C6H6Cl6 |
|---|---|
| Mol. Weight | 290.82 |
| Melting Point | 112.5°C |
| Flash Point | 11 °C |
| Density | 1.59 |
| Solubility | 不溶于水，溶于苯、丙酮、乙醚、煤油等。 |
别名和识别编码
| Chemical Name | 异辛烷中丙体六六六溶液标准物质(0.1ug/ml) |
|---|---|
| Synonym | {uni_hamburg} Dev 1,2,3,4,5,6-Hexachlorocyclohexane, gamma-iso 1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE [G-ISOMER] BBH Lacco HI lin γ-Hexachlorobenzene GAMMA-1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE γ-HCH Hexachlorane Cyclohexane, 1,2,3,4,5,6-hexachloro-, γ- APARASIN(R) Agrocide III γ-1,2,3,4,5,6 Linda γ-Hexachloran Cyclohexane, 1,2,3,4,5,6-hexachloro-, (1α,2α,3β,4α, 5α,6β)- Fenoform forte BHC (insecticide) Aphtiria Tri-6 Drilltox-Spezial Aglukon GAMMA-BHC DELTA-HCH Arbitex APHTIRIA Hexachlorocyclohexane, gamma-isomer Aparasin BHC agrocide iii Aficide benhexol hexachlorane bexol γ-Hexachlorane γ-六六六标准溶液 r-1,c-2,t-3,c-4,c-5,t-6-hexachlorocyclohexane {uni_ham Aalindan HEXA 林丹,(1α, 2α,3β,4α,5α,6β)-1,2,3,4,5,6-六氯 Ben-Hex γ-六六六标准溶液;林丹;(1α, 2α,3β,4α,5α,6β)-1,2,3,4,5,6-六氯环己烷;γ-六氯化苯;林旦;癣宁;(1A,2A,3B,4A,5A,6B)-1,2,3,4,5,6-六氯环己烷;灵丹;高丙体六六六;(1α,2α,3β,4α,5α,6β)-1,2,3,4,5 chlor γ-1,2,3,4,5,6-Hexac Detmol-extrakt γ-BHC 1α,2α,3β,4α,5α,6β-六氯环己烷 Γ-1,2,3,4,5,6-六氯环己烷 1,2,3 D-BHC DELTA-BENZENEHEXACHLORIDE {Chemical { 1ALPHA, 林丹,(1α, 2α,3β,4α,5α,6β)-1,2,3,4,5,6-六氯环己烷,γ-六氯化苯,γ-六六六,林旦,癣宁,(1A,2A,3B,4A,5A,6B)-1,2,3,4,5,6-六氯环己烷,灵丹,高丙体六六六,(1α,2α,3β,4α,5α,6β)-1,2,3,4,5,6-六氯环己烷 1,2,3,4,5 1,2,3,4,5,6-六氯环己烷 林丹 Kwell 林丹/GAMA-六六六 |
| CAS Number | 58-89-9 |
| EC Number | 200-401-2 |
| MDL Number | MFCD00135947 |
| PubChem Substance ID | 727 |
| Beilstein Registry Number | 1907337 |
| Chemical Name Translation | γ-六六六标准溶液 |
| Merck Number | 13,5523 |
| Wiswesser Line Notation | L6TJ AG BG CG DG EG FG GAMMA |
| InChI | InChI=1S/C6H6Cl6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h1-6H |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Acaricides,
- {SNA} Additional Standards, Analytical Standards, Chromatography, Food and Cosmetic Component Standards, Pharmaceutical Secondary Standards, Pharmaceutical Standards, Pharmacopeia & Metrological Institutes Standards, Secondary Standards, Standards for Personal Care and Cosmetic Products, neats, prohibited substances (EU-REGULATION No 1223/2009), 分析/色谱
- {uni_hamburg} no charge; carbocycle; alicycle; 6RingOnly; 6ring; 1fragment
- 2000/60/EC, A-B, Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, B, BA - BH, Bioactive Small Molecules, Cell Biology, C
产品应用
- 该品是作用于昆虫神经的广谱杀虫剂，兼有胃毒、触杀、熏蒸作用，一般加工成粉剂或可湿性粉剂使用。
相关文献及参考
- Merck:13,5523 Beilstein: 5,I,8
- Short: III/20b
- Short: III/5a
- Merck:13,5523
- Short: III/38B
安全信息
- H312+H332
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H362 May cause harm to breast-fed children 可能对母乳喂养的婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H301 Toxic if swallowed 吞食有毒
- H332 Harmful if inhaled 吸入有害
- H312 Harmful in contact with skin 皮肤接触有害
GHS Symbol
- P273 Avoid release to the environment. 避免释放到环境中。
- P263 Avoid contact during pregnancy/while nursing. 怀孕/哺乳期间避免接触。
- P301+P310+P330
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P302+P352+P312
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S29 Do not empty into drains 不要排入下水道；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R25 Toxic if swallowed 吞咽有毒
- R48/22
- R50/53
- R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
- R64 May cause harm to breast-fed babies 可能导致伤害脯乳期婴儿
- R11 Highly flammable 非常易燃
- R38 Irritating to skin 刺激皮肤
- R48/20
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R52/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性：吸入，皮肤接触和吞食都会产生十分严重的不可逆危险
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 14 gm/kg/2Y-C TOXIC EFFECTS : Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors REFERENCE : CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 8,1889,1987
TYPE OF TEST : TD - Toxic dose (other than lowest) ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 25 gm/kg/73W-C TOXIC EFFECTS : Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors REFERENCE : FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 11,433,1973
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 125 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold Gastrointestinal - changes in structure or function of salivary glands Nutritional and Gross Metabolic - weight loss or decreased weight gain REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 28(8),29,1963
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intracerebral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 60 mg/kg TOXIC EFFECTS : Behavioral - convulsions or effect on seizure threshold REFERENCE : TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 60,289,1992
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - hamster DOSE/DURATION : 360 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : EJTXAZ
TYPE OF TEST : TDLo - Lowe
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 120 mg/m3/6H TOXIC EFFECTS : Blood - changes in other cell count (unspecified) Blood - changes in leukocyte (WBC) count REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(10),55,1964
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Human Lymphocyte DOSE/DURATION : 5 mg/L REFERENCE : BIHAA2 Bibliotheca Haematologica (Basel). (S. Karger AG, Postfach, CH-4009 Basel, Switzerland) No.1- 1955- Volume(issue)/page/year: 38(Pt 1),344,1971
TYPE OF TEST : DNA inhibition TEST SYSTEM : Rodent - rat Cells - not otherwise specified DOSE/DURATION : 1 gm/L REFERENCE : ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 45,101,1980
TYPE OF TEST : Dominant lethal test ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 22 ug/L REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 33,309,1995
TYPE OF TEST : Unscheduled DNA synthesis TEST SYSTEM : Rodent - rat Liver DOSE/DURATION : 100 pmol/L REFERENCE : CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 5,1547,1984
TYPE OF TEST : Cytogenetic analysis TEST SYSTEM : Rodent - hamster Fibroblast DOSE/DURATION : 63 mg/L/48H REFERENCE : MUREAV Mutation Research. (Elsevier Scienc
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Oral TEST SYSTEM : Rodent - mouse DOSE/DURATION : 12600 ug/kg/7D (Continuous) REFERENCE : FCTOD7 Food and Chemical Toxicology. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.20- 1982- Volume(issue)/page/year: 33,309,1995
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE : 12500 ug/kg SEX/DURATION : female 16 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - maternal-fetal exchange REFERENCE : BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 47,508,1991
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Rodent - rat DOSE : 33 mg/kg SEX/DURATION : female 1 day(s) pre-mating TOXIC EFFECTS : Reproductive - Maternal Effects - other effects REFERENCE : TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 48,21,1989
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 43300 ug/kg SEX/DURATION : female 1-4 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) REFERENCE : TXCYAC Toxicology. (Elsevier Scientific Pub. Ireland, Ltd., POB 85, Limerick, Ireland) V.1- 1973- Volume(issue)/page/year: 59,171,1989
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE : 22500 ug/kg SEX/DURATION : female 14-19 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFE
其他信息
- 稳定性:Stable. Incompatible with strong oxidizing agents.
- 在常温下水中的溶解度为10ml/L，溶于丙酮、氯仿、芳香经，微溶于石油醚。
- EPA化学物质信息:Cyclohexane, 1,2,3,4,5,6-hexachloro-, (1.alpha.,2.alpha.,3.beta., 4.alpha.,5.alpha.,6.beta.)- (58-89-9)
- 毒害物质数据:58-89-9(Hazardous Substances Data)
- 杀虫剂单一组分标准液
- 生产方法:林丹是1，2，3，4，5，6-六氯环已烷的丙体（γ-体）。工业上含丙体99%以上的通称林丹，在六六六的甲、乙、丙、丁等构象异构体（即α-、β-、γ-、δ-体等）中，仅丙体具有强烈杀虫性质。林丹的工业生产方法是根据六六六各异构体在甲醇中不同温度下的溶解度不同，以及各种异构体的结晶度的差异来提取的，在适当的甲醇量及提取温度下，丙体、丁体及油状物杂质被抽出在甲醇中，甲、乙体成残渣分出。被饱和以及溶有丁体、油状物的甲醇溶液，经冷却结晶，因基结晶速度的差异，六六六丙体结晶分出。一般需再进行第二次提纯才能得到丙体含量在99%以上的林丹产品。
- 用途:用于防治水稻、小麦、大豆、玉米、蔬菜、果树、烟草、森林、粮仓等害虫
- 外观性质:白色晶体, 纯品无臭, 工业品有酸霉味。
- NIST化学物质信息:Lindane(58-89-9)
- MOL 文件:58-89-9.mol
- PackingGroup:III
- HazardClass:6.1(b)
- RTECS号:GV4900000
- 图谱信息:林丹(R-六六六)(58-89-9)红外图谱(IR1) 林丹(R-六六六)(58-89-9)核磁图( 13 CNMR) 林丹(R-六六六)(58-89-9)Raman光谱 林丹(R-六六六)(58-89-9)核磁图( 1 HNMR) 林丹(R-六六六)(58-89-9)质谱(MS) 林丹(R-六六六)(58-89-9)红外图谱(IR2)
- 毒性:大鼠急性经口LD 50 为88～270mg/kg(125mg/kg)，小鼠59～246mg/kg。对皮肤有刺激性，产生红疹和红肿。动物体内有蓄积用用，以625mg/kg喂养大鼠，约50%有抽蓄中毒症状，雄大鼠血清转氨酶活性增高，红细胞计数明显减少。生产车间最高允许浓度为0.5mg/m 3 。
