5-Bromo-2-Methoxyphenylboronic Acid (Contains Varying Amounts of Anhydride) 5-溴-2-甲氧基苯硼酸 (含有数量不等的酸酐)
CAS 89694-45-1 MFCD00093409
化学结构图
SMILES: COC1C=CC(Br)=CC=1B(O)O
化学属性
| Mol. Formula | C7H8BBrO3 |
|---|---|
| Mol. Weight | 230.85 |
| Melting Point | 130-135 °C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | 5-Bromo-2-Methoxyphenylboronic Acid (Contains Varying Amounts of Anhydride) |
|---|---|
| Synonym | 5-溴-2-甲氧基苯硼酸 3-Bromo-6-methoxyphenylboronic acid 5-Bromo-2-methoxybenzeneboronic acid 3-Bromo-6-methoxyphenylboronic acid 5-Bromo-2-methoxybenzeneboronic acid 5-Bromo-2-methoxyphenylboronic acid |
| MDL Number | MFCD00093409 |
| PubChem Substance ID | 354335378 |
| CAS Number | 89694-45-1 |
| Chemical Name Translation | 5-溴-2-甲氧基苯硼酸 (含有数量不等的酸酐) |
| Reaxys-RN | 3031445 |
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分类
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 2. Kuethe, J. T.; Childers, K. G. , Suzuki-Miyaura cross-coupling of 2-nitroarenediazonium tetrafluoroborates: synthesis of unsymmetrical 2-nitrobiphenyls and highly functionalized carbazoles Adv. Synth. Catal. 350 , 1577-1586, (2008)
- 3. Noguchi, H.; et al., Boron-Masking Strategy for the Selective Synthesis of Oligoarenes via Iterative Suzuki-Miyaura Coupling J. Am. Chem. Soc. 129 , 758-759, (2007)
- 1. Suzaki, Y.; et al., Tweezers-like aromatic molecules and their luminescent properties depending on the structures Tetrahedron Lett. 52 , 3883-3885, (2011)
- Beil. 16 ,IV,1681
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
