(2S,5S)-Hexane-2,5-diol (2S,5S)-2,5-己二醇

CAS 34338-96-0 MFCD00082583

化学结构图

34338-96-0
SMILES: CC(O)CCC(C)O

化学属性

Mol. FormulaCH3CH(OH)CH2CH2CH(OH)CH3
Mol. Weight118
Boiling Point71°C/1mmHg(lit.)
Melting Point52.0 to 56.0 deg-C
Flash Point101°(215°F)
TSCANo

别名和识别编码

Chemical Name(2S,5S)-Hexane-2,5-diol
CAS Number34338-96-0
Synonym (2S,5S)-2,5-己二醇 [S-(R*,R*)]-
PubChem Substance ID87571325
Beilstein Registry Number1(3)2204
MDL NumberMFCD00082583
Reaxys-RN4652444
Chemical Name Translation(2S,5S)-2,5-己二醇
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyols

产品应用

  • Used in the synthesis of new phospholanes. Reagent used for asymmetric syntheses.

相关文献及参考

  • Uppenberg, J., et al.: Biochemistry, 34, 16838 (1995),
  • 1. Tetrahedron Asymmetry 2 , 569, (1991)
  • 2. J. Org. Chem. 54 , 1755, (1989)
  • 3. Marshall, J.A. Xie, S. J. Org. Chem. 60 , 7230, (1995)
  • 4. Stolle, A. et al. Tetrahedron Lett. 35 , 3521, (1994)
  • 5. Burk, M.J. et al. J. Am. Chem. Soc. 115 , 10125, (1993)
  • 6. Burk, M.J. et al. Tetrahedron Asymmetry 2 , 569, (1991)
  • 7. Pichon, M. Figadere, B. Tetrahedron Asymmetry 7 , 927, (1996)
  • 8. Matteson, D.S. Man, H.-W. J. Org. Chem. 59 , 5734, (1994)
  • 9. Ho, O.C. et al. Organometallics 14 , 2855, (1995)
  • Beil. 1 ,III,2204
  • FT-IR 2 (1), 194:B / Structure Index 1 , 17:D:5

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害

系列性分类


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