CAS 65012-74-0 MFCD00078983-(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate (双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I) TAO{mole}

(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate (双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I)

CAS 65012-74-0 MFCD00078983

化学结构图

SMILES: [Rh+].C[C@@H]([C@H](C)P(C1C=CC=CC=1)C1C=CC=CC=1)P(C1C=CC=CC=1)C1C=CC=CC=1.[O-]Cl(=O)(=O)=O.C1C2C=CC1C=C2

化学属性

Mol. Formula	C35H32ClO4P2Rh
Mol. Weight	716.93
Melting Point	210 °C (dec.)(lit.)

别名和识别编码

Chemical Name	(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-bis(diphenylphosphino)butane]rhodium(I) perchlorate
MDL Number	MFCD00078983
PubChem Substance ID	24860271
Synonym	(双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I)
Chemical Name Translation	(双环[2.2.1]庚-2,5-二烯)[(2S,3S)-二(二苯基膦基)丁烷]高氯酸铑(I)
CAS Number	65012-74-0

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安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
H319 Causes serious eye irritation 严重刺激眼睛

Signal word Danger

Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Hazard Codes O,Xi

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S17 Keep away from combustible material 远离可燃物料；

Risk Statements

R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性