CAS 8018-01-7 MFCD00078616-Mancozeb 代森锰锌 TAO{mole}

Mancozeb 代森锰锌

CAS 8018-01-7 MFCD00078616

化学结构图

SMILES: NC(=S)SCCSC(N)=S.[Mn].[Zn]

化学属性

Mol. Formula	C4H6MnN2S4.C4H6N2S4Zn
Mol. Weight	541.03
Flash Point	138 °C
Appearance	灰黄色粉末。熔融前分解。实际上不溶于水和大多数有机溶剂。在通常贮存条件下稳定，但在潮湿和酸性条件下，温度升高就会分解。
Melting Point	192-194°C

别名和识别编码

Chemical Name	Mancozeb
Synonym	MANCOZEB Tritogol MZ Dithane M 45 ((1,2-Ethanediylbis(carbamodithioato)))manganese mixture with ((1,2-ethandiylbis(carbamodithioate)))zinc Thane M45 Kascade 亚乙基双(二硫代氨基甲酸)锰锌 Agrox 16D Manzate 200 Marzidan ZINC AND MANGANESE ETHYLENE-BISDITHIOCARBAMATE COORDINATION PRODUCT Mancozeb [1,2-亚乙基-双(二硫代氨基甲酸)]锰锌盐 MANCOZEB STANDARD CRITTOX Fore 锌猛乃浦 Mancomix Penncozeb MANEX II Green-daisen M Dithane SPC Maneb-zineb-mischkomplex Dithane ultra TRIDEX(R) FUNGICIDE Karamate Nemispor Mancofol Zimaneb Maneb-zinc Zineb-maneb mixt. 亚乙基双(二硫代氨基甲酸锰) + 亚乙基双(二硫代氨基甲酸锌) Mancozi DITHANE(R) Carbamic acid, ethylenebis(dithio-, manganese zinc complex MICENE Novozir MN 80 MANZATE(R) 代森锰锌可湿性粉剂(50%) Dithane S 60 Carmazine ｛[1,2-亚乙基-双(二硫代氨基甲酸)](2-)｝锰锌盐 MANCO Tanzeo M45 Marzin MANGANESE-ZINC ETHYLENEBIS(DITHIOCARBAMATE) DITHANE Manzeb PENNCOZEB(R) TRIMANOC(R) VONDOZEB FORE(R) 叶斑青 Manoseb Manzin 80 Ziman-Dithane PENNFLUID(R) AIMCOZEB Mangan-zink-aethylendiamin-bis-dithio-carbamat Othane M 45 F 2966 Maneb-zineb-komplex MANZEB 代森锰锌 Zimanat
MDL Number	MFCD00078616
CAS Number	8018-01-7
Chemical Name Translation	代森锰锌
Merck Number	13,5738
PubChem Substance ID	13307026
InChI	InChI=1S/2C4H8N2S4.Mn.Zn/c27-3(8)5-1-2-6-4(9)10;;/h21-2H2,(H2,5,7,8)(H2,6,9,10);;/q;;2*+2/p-4

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安全信息

RTECSZB3200000

GHS Symbol

WGK Germany1

Precautionary statements

P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P308+P313
P201 Obtain special instructions before use. 使用前获取专门指示。
P333+P313

Signal word Warning

Hazard statements

H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害

Hazard Codes Xn,N Xi

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Packing GroupIII

Hazard Class9

Storage condition APPROX 4°C

UN Number UN 2210

Safety Statements

S46 If swallowed, seek medical advice immediately and show this container or label 食入时，立即求医并出示容器/标签；
S8 Keep container dry 保持容器干燥；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R50 Very toxic to aquatic organisms 对水生生物极毒
R37 Irritating to respiratory system 刺激呼吸道

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 17700 mg/kg/60W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   53,191,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A251,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd,
   eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year:
   A251,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PEMNDP Pesticide Manual.  (The British Crop Protection Council, 20 Bridport
   Rd., Thornton Heath CR4 7QG, UK)  V.1-    1968-  Volume(issue)/page/year:
   9,530,1991

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 50 ppm
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB85-193761

TYPE OF TEST            : Mutation in mic

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 2500 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,341,1983

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 10 mg/L
REFERENCE :
   NTIS** National Technical Information Service.  (Spring

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 476 mg/kg/40W (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,341,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 12 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 176,29,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 4 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 116,341,1983

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1320 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - craniofacial
   (including nose and tongue)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
   Reproductive - Specific Developmental Abnormalities - homeostasis
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 14,171,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2500 mg/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   KHZDAN Khigiena i Zdraveopazvane.  Hygiene and Sanitation.  (Hemus, Blvd.
   Russki 6, Sofia, Bulgaria) V.9-    1966-  Volume(issue)/page/year:
   27,524,1984

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 500 mg/m3/6H
SEX/DURATION            : female 6-10 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(i

其他信息

用途一:为高效、低毒、广谱保护性杀菌剂，用于小麦、玉米、水果等作物的杀菌防病
用途四:该品为广谱的叶面保护用杀菌剂，广泛用于果树；蔬菜以及大田作物，可防治多种重要的叶部真菌病害，例如麦类锈病，玉米大斑病，马铃薯疫霉病，果树黑星病，炭疽病等。其用量为1.4-1.9kg（有效成分）/hm2。由于它用途广；药效好，已成为非内吸性的保护杀菌剂中的重要品种。与内吸性杀菌剂轮换使用或混用，可有一定的销路。
上游原料:氢氧化铵 --> 氨 --> 氯化锌 --> 二硫化碳 --> 乙二胺 --> 硫酸锌 --> 碳酸锰 --> 硫酸锰 --> 七水硫酸锌 --> 硫酸锰 --> 代森锰 --> 硝酸锌 --> 代森钠
中毒症状:恶心、呕吐、腹痛、腹泻，头痛、头晕、乏力，严重者可导致呼吸和循环功能衰竭加快，血压下降，呼吸抑制等。
用途三:该品为广谱的叶面保护用杀菌剂，广泛用于果树、蔬菜以及大田作物，可防治多种重要的叶部真菌病害，例如麦类锈病，玉米大斑病，马铃薯疫霉病，果树黑星病，炭疽病等。其用量为1.4-1.9kg（有效成分）/hm2。由于它用途广、药效好，已成为非内吸性的保护杀菌剂中的重要品种。与内吸性杀菌剂轮换使用或混用，可有一定的销路。
注意事项:(1)该药不能与铜及强碱性农药混用，在喷过铜、汞、碱性药剂后要间隔一周后才能喷此药 (2)在茶树上的间隔期为半个月
下游产品:代森锰 --> 代森锰锌可湿性粉剂 --> 腈菌·锰锌可湿性粉剂 --> 锰锌·烯酰可湿性粉剂
用途二:属广谱性杀菌剂，用于防治农作物因真菌引起的各种病害
Sigma Aldrich:8018-01-7(sigmaaldrich)
MSDS 信息:Mancozeb(8018-01-7).msds
方法一:将代森钠与浓氯化锰液等量反应，制得浆状代森锰液。然后，将代森锰与硝酸锌或硫酸锌溶液反应，喷雾干燥得到产品。原料消耗定额：乙二胺（98%）310kg/t、二硫化碳（99%）870kg/t、氢氧化钠（30%）420kg/t、硫酸锰（98%）1020kg/t、硫酸锌（96%）80kg/t。
MOL 文件:8018-01-7.mol
急救治疗:[1]误食者立即催吐、洗胃、导泻。 [2]对症治疗。 [3]忌油类食物，禁酒。